Full Paper View Go Back

Solar light assisted photocatalytic degradation of hazardous and highly water soluble pesticide Methomyl using Flower like nano BiOCl

B. Pare1 , S. Piplode2 , V. Joshi3

  1. Dept. of Chemistry, J. N. S. Govt. College (Vikram University), Shujalpur, India.
  2. Dept. of Chemistry, Govt. Madhav Science College (Vikram University), Ujjain, India.
  3. Dept. of Chemistry, Govt. Madhav Science College (Vikram University), Ujjain, India.

Correspondence should be addressed to: satish.piplode@gmail.com.


Section:Research Paper, Product Type: Isroset-Journal
Vol.5 , Issue.5 , pp.5-11, Oct-2017


CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v5i5.511


Online published on Oct 30, 2017


Copyright Š B. Pare, S. Piplode, V. Joshi . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

View this paper at   Google Scholar | DPI Digital Library


XML View     PDF Download

How to Cite this Paper

  • IEEE Citation
  • MLA Citation
  • APA Citation
  • BibTex Citation
  • RIS Citation

IEEE Style Citation: B. Pare, S. Piplode, V. Joshi, “Solar light assisted photocatalytic degradation of hazardous and highly water soluble pesticide Methomyl using Flower like nano BiOCl,” International Journal of Scientific Research in Physics and Applied Sciences, Vol.5, Issue.5, pp.5-11, 2017.

MLA Style Citation: B. Pare, S. Piplode, V. Joshi "Solar light assisted photocatalytic degradation of hazardous and highly water soluble pesticide Methomyl using Flower like nano BiOCl." International Journal of Scientific Research in Physics and Applied Sciences 5.5 (2017): 5-11.

APA Style Citation: B. Pare, S. Piplode, V. Joshi, (2017). Solar light assisted photocatalytic degradation of hazardous and highly water soluble pesticide Methomyl using Flower like nano BiOCl. International Journal of Scientific Research in Physics and Applied Sciences, 5(5), 5-11.

BibTex Style Citation:
@article{Pare_2017,
author = {B. Pare, S. Piplode, V. Joshi},
title = {Solar light assisted photocatalytic degradation of hazardous and highly water soluble pesticide Methomyl using Flower like nano BiOCl},
journal = {International Journal of Scientific Research in Physics and Applied Sciences},
issue_date = {10 2017},
volume = {5},
Issue = {5},
month = {10},
year = {2017},
issn = {2347-2693},
pages = {5-11},
url = {https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=474},
doi = {https://doi.org/10.26438/ijcse/v5i5.511}
publisher = {IJCSE, Indore, INDIA},
}

RIS Style Citation:
TY - JOUR
DO = {https://doi.org/10.26438/ijcse/v5i5.511}
UR - https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=474
TI - Solar light assisted photocatalytic degradation of hazardous and highly water soluble pesticide Methomyl using Flower like nano BiOCl
T2 - International Journal of Scientific Research in Physics and Applied Sciences
AU - B. Pare, S. Piplode, V. Joshi
PY - 2017
DA - 2017/10/30
PB - IJCSE, Indore, INDIA
SP - 5-11
IS - 5
VL - 5
SN - 2347-2693
ER -

561 Views    168 Downloads    187 Downloads
  
  

Abstract :
Flower like nano bismuth oxy chloride (BiOCl) was successfully synthesized by a simple hydrolytic method using Bi (NO3)3.5H2O as Bi source material at room temperature. The as-prepared samples were characterized by X-ray diffraction (XRD), High Resolution Field Emission Scanning Electron Microscope (HR FESEM). The results indicated that the as-prepared BiOCl sample is self-assembled hierarchically with nano sheets. The photocatalytic activity of BiOCl was tested on the degradation of the methomyl under solar light irradiation. The results showed that pesticide molecules could be efficiently degraded over BiOCl under solar light irradiation.

Key-Words / Index Term :
BiOCl, Flowerlike, Pesticide, photocatalysis, methomyl, solar light

References :
[1] C.D.S. Tomlin (Ed.), “The Pesticide Manual”, 13 Ed, BCPC, Hampshire, pp 697–698, 2006.
[2] S. Malato, J. Blanco, J. C´aceres, A.R. Fern´andez-Alba, A. Ag¨uera, A. Rodr´ıguez, “Photocatalytic treatment of water-soluble pesticides by photo-Fenton and TiO2 using solar energy”, Catal. Today, vol 76, pp 209–220, 2002.
[3] S. Malato, J. Blanco, A. Vidal, D. Alarc´on, M.I. Maldonado, J. C´aceres, W. Gernjak, “Applied studies in solar photocatalytic detoxification: an overview”, Sol. Energy, vol 75, pp 329–336, 2003.
[4] M. Tamimi, S. Qourzal, A. Assabbane, J.-M. Chovelon, C. Ferronato, Y. Ait-Ichou, “Photocatalytic degradation of pesticide methomyl: determination of the reaction pathway and identification of intermediate products”, Photochem. Photobiol. Sci., vol 5, pp 477–482, 2006.
[5] I. Oller, W. Gernjak, M.I. Maldonado, L.A. Pérez-Estrada, J.A. Sánchez-Pérez, S. Malato, “Solar photocatalytic degradation of some hazardous water-soluble pesticides at pilot-plant scale”, J. Hazard. Mater., vol B 138,pp 507–517, 2006.
[6] A.TomaĹĄević, D. Mijin and E.Kiss, “Photochemical Behavior of the Insecticide Methomyl Under Different Conditions”, Separation Science and Technology, vol 45, pp 1617 -27, 2010.
[7] R.-S. Juang and C.-H.Chen, “comparative study on photocatalytic degradation of methomyl and parathion over UV-irradiated TiO2 particles in aqueous solutions”, Journal of the Taiwan Institute of Chemical Engineers, vol. 45, Issue 3, pp 989–995, 2014.
[8] N. A. M.Barakat, M. M.Nassar, T. E. Farrag and M. S. Mahmoud, “effective photodegradation of methomyl pesticide in concentrated solutions by novel enhancement of the photocatalytic activity of TiO2 using CdSO4 nanoparticles”, Environ SciPollut Res, vol. 21, pp 1425-1435, 2014.
[9] A.TomaĹĄević, D.Mijin, S. GaĹĄic and E.Kiss, “the influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension”, Desalination and Water Treatment, vol. 52, pp 4342-4349, 2014.
[10] M. Tamimi, S. Qourzal, N. Barka, A. Assabbane, Y. Ait-Ichou, “Methomyl degradation in aqueous solutions by Fenton’s reagent and the photo-Fenton system”, Separation and Purification Technology, vol. 61,pp 103–108, 2008.
[11] A .R. Fernández-Alba, D. Hernando, A. Agüera, J. Cáceres, S. Malato, “Toxicity assays: a way for evaluating AOPs efficiency”, Water Res., vol. 36, pp 4255–4262, 2002.
[12] A. TomaĹĄević, G. BoĹĄković, D. Mijin, E.E. Kiss, “Decomposition of methomyl over supported iron catalysts”, React. Kinet. Catal. Lett., vol. 91, pp 53–59, 2007.
[13] A TomaĹĄević, E Kiss, S Petrović , D Mijin, “Study on the photocatalytic degradation of insecticide methomyl in water”, Desalination, vol. 262, pp 228–234, 2010.
[14] A. Zapata, I. Oller, E. Bizani, J. A. Sanchez-Perez, M. I. Maldonado, S. Malato, “Evaluation of operational parameters involved in solar photo-Fenton degradation of a commercial pesticide mixture”, Catalysis Today, vol. 144, pp 94–99, 2009.
[15] Fares A. Al Momani, Ahmad T. Shawaqfeh, Mo‘ayyed S. Shawaqfeh, “Solar wastewater treatment plant for aqueous solution of pesticide”, Solar Energy, vol. 81, pp 1213–1218, 2007.
[16] S. Malato, P. Fernandez-Ibanez, M.I. Maldonado, J. Blanco, W. Gernjak, “Decontamination and disinfection of water by solar photocatalysis: Recent overview and trends”, Catalysis Today, vol. 147, pp 1–59, 2009.
[17] P. Ye , J. Xie, Y. He, L. Zhang, T. Wu, Y. Wu,“Hydrolytic synthesis of flower like BiOCl and its photocatalytic performance under visible light”, Materials Letters, vol. 108, pp 168–171, 2013.
[18] Z. Y. Jiang, Q. Kuang, Z. X. Xie, L. S. Zheng, “Syntheses and Properties of Micro/Nanostructured Crystallites with High-Energy Surfaces”, Advanced Functional Materials, vol. 20 Issue 21, pp 3634–3645, 2010.
[19] M. S. S. Dorraji, N. Daneshavar and S. Aber, “Influence of inorganic oxidants and metal ions on photocatalytic activity of prepared zinc oxide nanocrystals”, J. Glob. Nest, vol. 11, Issue 4,pp 535-545, 2009.
[20] F. Sayılkan, M. AsiltĂźrk, P. Tatar, N. Kiraz, S. Sener, E. Arpac and H. Sayılkan, “Photocatalytic performance of Sn-doped TiO2 nanostructured thin films for photocatalytic degradation of malachite green dye under UV and VIS-lights”, Mater. Res. Bull., vol. 43 Issue 1,pp 127-134, 2008.
[21] I. Poulios, A. Avranas, E. Rekliti and A. Zouboulis, “Photocatalytic oxidation of Auramine O in the presence of semiconducting oxides”, J. Chem. Technol. Biotechnol., vol. 75, pp 205-212, 2000.
[22] B. Pare, P. Singh and S. B. Jonnalagadda, “Visible light induced heterogeneous advanced oxidation process to degrade pararosanilin dye in aqueous suspension of ZnO”, Indian J Chem A, vol. 47A, Issue 6, pp 830-835, 2008.
[23] B. Pare, P. Singh and S. B. Jonnalgadda, “Degradation and mineralization of victoria blue B dye in a slurry photoreactor using advanced oxidation process”, J. Scient. Ind. Res., vol. 68, Issue 8, pp 724-729, 2009.
[24] M. A. Benajady, N. Modirshala and R. Hamzavi, “Kinetic study on photocatalytic degradation of C.I. Acid Yellow 23 by ZnOphotocatalyst”, J. Hazard. Mat. , vol. 133. Issue 1-3, pp 226-232, 2006.
[25] D. Ma, S. Huang, W. Chen, S. Hu, F. Shi, and K. Fan, “Self-Assembled Three-Dimensional Hierarchical Umbilicate Bi2WO6 Microspheres from Nanoplates: ControlledSynthesis, Photocatalytic Activities, and Wettability”, J. Phys. Chem. C, vol. 113, Issue 11, pp 4369-4374, 2009.
[26] H. Li, Z. Bian, J. Zhu, D. Zhang, G. Li, Y. Huo, H. Li, and Y. Lu, “Mesoporous Titania Spheres with Tunable Chamber Stucture and Enhanced Photocatalytic Activity”, J Am Chem Soc, vol. 129, Issue 27 , pp 8406–7, 2007.
[27] K. L. Zhang, C. M. Liu, F. Q. Huang, C. Zheng and W. D. Wang, “Study of the electronic structure and photocatalytic activity of the BiOCl photocatalyst”, Appl. Catal. B Environ., vol. 68, Issue 3-4, pp 125-129, 2006.

Authorization Required

 

You do not have rights to view the full text article.
Please contact administration for subscription to Journal or individual article.
Mail us at  support@isroset.org or view contact page for more details.

Go to Navigation