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Effect of bismuth sulfide on the electrical properties of polyethylene oxide based polymer electrolyte

Manoj Kumar1

  1. Department of Physics, D.A.V. College, Abohar, India.

Correspondence should be addressed to: mkverma782006@gmail.com.


Section:Research Paper, Product Type: Isroset-Journal
Vol.6 , Issue.3 , pp.25-30, Jun-2018


CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v6i3.2530


Online published on Jun 30, 2018


Copyright © Manoj Kumar . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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IEEE Style Citation: Manoj Kumar, “Effect of bismuth sulfide on the electrical properties of polyethylene oxide based polymer electrolyte,” International Journal of Scientific Research in Physics and Applied Sciences, Vol.6, Issue.3, pp.25-30, 2018.

MLA Style Citation: Manoj Kumar "Effect of bismuth sulfide on the electrical properties of polyethylene oxide based polymer electrolyte." International Journal of Scientific Research in Physics and Applied Sciences 6.3 (2018): 25-30.

APA Style Citation: Manoj Kumar, (2018). Effect of bismuth sulfide on the electrical properties of polyethylene oxide based polymer electrolyte. International Journal of Scientific Research in Physics and Applied Sciences, 6(3), 25-30.

BibTex Style Citation:
@article{Kumar_2018,
author = {Manoj Kumar},
title = {Effect of bismuth sulfide on the electrical properties of polyethylene oxide based polymer electrolyte},
journal = {International Journal of Scientific Research in Physics and Applied Sciences},
issue_date = {6 2018},
volume = {6},
Issue = {3},
month = {6},
year = {2018},
issn = {2347-2693},
pages = {25-30},
url = {https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=628},
doi = {https://doi.org/10.26438/ijcse/v6i3.2530}
publisher = {IJCSE, Indore, INDIA},
}

RIS Style Citation:
TY - JOUR
DO = {https://doi.org/10.26438/ijcse/v6i3.2530}
UR - https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=628
TI - Effect of bismuth sulfide on the electrical properties of polyethylene oxide based polymer electrolyte
T2 - International Journal of Scientific Research in Physics and Applied Sciences
AU - Manoj Kumar
PY - 2018
DA - 2018/06/30
PB - IJCSE, Indore, INDIA
SP - 25-30
IS - 3
VL - 6
SN - 2347-2693
ER -

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Abstract :
Polymer electrolytes based on the polyethylene oxide and ammonium perchlorate (PEO: NH4ClO4) dispersed with bismuth sulfide are successfully prepared by in situ method. The electrical characterization of different samples is done by complex impedance spectroscopy, conductivity dispersion curve and Wagner polarization technique. Complex impedance plots are the semicircles and the intercept on the real axis showed the value of the bulk conductivities (10-6 - 10-5 S/cm-1) of the different polymeric samples. The overall conductivity of polymer electrolyte is enhanced with the dispersal of bismuth sulfide, peaks at 6 wt. % then decreases which could be explained by Bunde et al model. Detailed I-V studies show n-type behavior of dispersoid in the composite.

Key-Words / Index Term :
Polymer electrolyte composites, complex impedance spectroscopy, bulk electrical conductivity

References :
[1] P.V. Wright, “Electrical conductivity in ionic complexes of poly(ethylene oxide),” British Polymer Journal. vol 7: pp.319-327,1975.
[2] D.E. Fenton, J.M. Parker, P.V. Wright, “Complexes of alkali metal ions with poly(ethylene oxide)”, Polymer. 14 pp. 589-589, 1973.
[3] J.R. MacCallum, C.A. Vincent, “Polymer Electrolyte Reviews”, 1, 2, Elsevier, New York 1989, 1991.
[4] S. Chandra. “Superionic solids: Principles and Applications”, North Holland, Amsterdam. 1981.
[5] A.F. Nogueira, J.R. Durrant, M.A. De Paoli. “Dye-Sensitized Nanocrystalline Solar Cells Employing a Polymer Electrolyte”, Advanced Materials, Vol.13 pp.826-830, 2001.
[6] A. Chandra, S. Chandra, “Experimental observation of large-size fractals in ion-conducting polymer electrolyte films”, Physical Review B. Vol.49, pp.633-636, 1994.
[7] S. A. Hashmi, A. Kumar and K. K. Maurya et.al, “Proton-conducting polymer electrolyte I, The polyethylene oxide+NH4ClO4 system”, Journal Physics. D, Vol.23 pp.1307-1314, 1990.
[8] W. Wang, P. Alexandridis, “Composite Polymer Electrolytes: Nanoparticles Affect Structure and Properties”, Polymers, Vol.8, pp.387, 2016.
[9] A. Arya, A.L. Sharma, “Conductivity and Stability Properties of Solid Polymer Electrolyte Based on PEO-PAN + LiPF6 for Energy Storage”, Applied Science Letter, Vol.2, pp.72-75, 2016.
[10] R.J. Sengwa, S. Choudhary, P. Dhatarwal, “Influences of ultrasonic- and microwave-irradiated preparation methods on the structural and dielectric properties of (PEO–PMMA)–LiCF3SO3–x wt% MMT nocomposite electrolytes” Ionics, Vol.2, pp. 95-109, 2015.
[11] A. Arya, A.L. Sharma and S. Sharma et.al. “Role of low salt concentration on electrical conductivity in blend polymeric films”, Journal integrated Science & Technology, Vol.4, pp.17-20, 2016.
[12] M. Kumar and S.S. Sekhon, “Role of plasticizer`s dielectric constant on conductivity modification of PEO–NH4F polymer electrolytes. European Polym J. Vol.38, pp.1297-1304, 2002.
[13] A. Arya, A.L. Sharma. “Polymer electrolytes for lithium ion batteries”, a critical study, Ionics, Vol.23: Issue 3, pp.497-540, 2017.
[14] A. Chandra P.K. Singh, S. Chandra. ”Semiconductor-dispersed polymer electrolyte composites”, Solid State Ionics, Vol.154, pp.15-20, 2002.
[15] P.K. Singh, S. Chandra and A. Chandra, “Polymer electrolyte composites with dispersed semiconductors”, Journal of Material Science Letter, Vol.21, pp.1393-1395, 2002.
[16] M. Kumar, A. Chandra, “In situ production of CuS particles in polymer electrolyte matrix for mixed ion+electron conduction”, Ionics”, Vol.16, pp.849-853 2010.
[17] M. Kumar, “Synthesis, electrical and thermal properties of PEO: NH4ClO4-camphor sulfonic acid-doped polyaniline composite”, Materials Express. Vol.7: pp.223-229, 2017.
[18] M. Kumar, J.P. Sharma, “Electrical and Optical Studies of PVA Based Polymer Gel”, Electrolytes” Material focus Vol.5, pp.1-6, 2016
[19] J. Maier, “Enhancement of the Ionic Conductivity in Solid-Solid-Dispersions by Surface Induced Defects”, Ber Bunsenges Phys Chem, Vol.88, pp.1057-1062, 1984.
[20] A. Bunde, W. Dietrich, E. Roman, Dispersed ionic conductors and percolation theory. Physical Review Letter. Vol.55, pp.5-8, 1985.
[21] C. Wagner. proc. 7th meeting C.I.T.C.E., Lindau, Butterwords, Londan, pp. 361, 1957.

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