Synthesis and Characterization of 2-Chloro-6-fluorobenzylalcohol using Electrochemical Approach

Ritu Saharan¹

Section:Research Paper, Product Type: Isroset-Journal
Vol.5 , Issue.4 , pp.17-20, Aug-2018

CrossRef-DOI:   https://doi.org/10.26438/ijsrbs/v5i4.1720

Online published on Aug 31, 2018

Copyright © Ritu Saharan . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

View this paper at   Google Scholar | DPI Digital Library

XML View     PDF Download

How to Cite this Paper

505 Views    377 Downloads    177 Downloads

Abstract :
Electrochemical Synthesis and characterization of 2-Chloro-6-fluorobenzylalcohol is investigated. The electrochemical behavior and electrochemical reduction of 2-Chloro-6-flourobenzaldehydeis has been carried out using cyclic voltammetry having glassy carbon electrode (GCE) and constant current electrolysis respectively. Reduction reaction peaks at various scan rate and pH has been reported. In kinetic parameters study, the process has been found to be diffusion controlled. The synthesized 2-Chloro-6-fluorobenzylalcohol has been characterized using IR, 1HNMR and Mass spectral analysis.

Key-Words / Index Term :
Cyclic voltammetry, Electrochemical Synthesis, Constant current electrolysis, Glassy carbon electrode, Electrochemical reduction

References :
[1] B. Devadas, M. Rajkumar, S. M. Chen, R. Saraswathi, “Electrochemically Reduced Graphene oxide/ Neodymium Hexacynoferrate Modified Electrodes for the electrochemical Detection of paracetamol”, Int. J. Electrochem. Sci., Vol. 7, pp. 3339-3349, 2012
[2] RE Clarke, A Kulkarni, S Giddey et al. “Evaluation of solid electrolyte cells with a versatile electrochemical techniques”, Ionics, 19, pp. 265-275, 2013, DOI: 10.1007/s11581-012-0749-1.
[3] R. Saharan, “Electrochemical Synthesis and Characterization of 2, 4-Dichlorobenzylalcohol”, Ascent International Journal for Research Analysis, Vol. II, Issue IV, 2.1–2.5, 2017
[4] T. Shano, “Electro-organic Chemistry as a New Tool in Organic Synthesis”, Springer, New York, 1984.
[5] D. Nematollahi and A. Amani, “Electrochemical synthesis of the new substituted phenylpiperazines”, J. Electroanal. Chem., Vol. 651, Issue1, pp.72-79, 2011
[6] F.R Perez, L. Basaez , J. Belmar and P. Vanysek, “Cyclic voltammetry of 1-(N-hexyl)-3-methyl-5-pyrazolone-based enamines and their chloromanganese(III) and nitridomanganese (V) complexes”, J. Chil. Chem. Soc., Vol. 50, Issue 3, pp. 575-580, 2005
[7] A Masek, M Zaborski, E Chrzescijanska, “Electro-oxidation of flavonoids at platinum electrode studied by cyclic voltammetry”, Food Chem.,Vol. 127 Issue 2, pp. 699-704, 2011
[8] N.G. Tsierkezos, “Investigation of the electrochemical reduction of benzophenone in aprotic solvents using the method of cyclic voltammetry” J. Solution Chem, Vol. 36(10), pp.1301-1310, 2007
[9] ME Niyazymbetov, “Electrochemical methods in organic synthesis of valuable intermediates” Electrosynthesis, Vol. 3 Issue 2, 1997
[10] GP Mamatha, BS Sherigara, KM Mahadevan, “Electrochemical reduction of 2-acetyl benzofuran and its derivatives at glassy carbon electrode”, Indian Journal of Chemical Technology, 14, pp. 566-571, 2007,
[11] R. Saharan, J. Joshi, “Synthesis, characterization and antibacterial studies of 4-Hydroxy-3-methoxy-benzyl alcohol and 1-(4-Hydroxy-3-methoxyphenyl) ethanol”, Journal of Biological and Chemical Research, 33 Issue1, pp. 529-536, 2016
[12] R. Saharan, “Analysis of Antibacterial Properties of 2-Methylcyclohexanol”, International Journal of Scientific Research and Review, Vol. 7 Issue 6, pp. 347-351, 2018