Sorption Investigation of Metal Ions by Copolymers with Respect to pH, Time and in Media of Different Ionic Strength

Pawan P. Kalbende¹

Section:Research Paper, Product Type: Isroset-Journal
Vol.5 , Issue.6 , pp.5-18, Dec-2018

CrossRef-DOI:   https://doi.org/10.26438/ijsrcs/v5i6.518

Online published on Dec 31, 2018

Copyright © Pawan P. Kalbende . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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Abstract :
A series of acid catalysed condensation copolymers has been synthesized by using p-nitrophenol, 4,4’-methylenedianilne and formaldehyde with different molar proportions of reacting monomers. Newly synthesized copolymers were proved to be selective chelating ion-exchangers for metal ions like Fe3+, Cu2+, Ni2+, Co2+, Zn2+, Cd2+, Hg2+ and Pb2+ ions. A batch equilibrium method has been employed in the study of selectivity of metal ion uptake involving the distribution of given metal ions between the copolymer and a solution containing metal ion. The study was carried out over a wide pH range, shaking time, temperature and in media of various ionic strengths of different electrolytes. Distribution ratios of metal ions were found to be increased by increasing pH of solutions; hence the resins can be used to recover certain metal ions from waste solution. Sorption data obtained at optimized conditions were analyzed by Langmuir and Freundlich adsorption isotherm models. The adsorption process follows first order kinetics and specific rate constant (Kr) was obtained by the application of Langargren equation. Thermodynamic parameters viz. ΔG, ΔS and ΔH have also been calculated for the metal-resin system.

Key-Words / Index Term :
Ion-exchange; Batch equilibrium; Metal ion uptake; Distribution ratio; Isotherm; Thermodynamics

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