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Bleaching Efficiency of Ortho-Phosphoric Acid Activated Kaolin Clay Sample on Crude Palm Oil Colour Pigment Removal

R.E. Nnam1 , J.K. Anozie2 , N.J. Emerenini3 , N.U. Okoro4

Section:Research Paper, Product Type: Journal-Paper
Vol.7 , Issue.6 , pp.12-20, Dec-2020


Online published on Dec 31, 2020


Copyright © R.E. Nnam, J.K. Anozie, N.J. Emerenini, N.U. Okoro . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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IEEE Style Citation: R.E. Nnam, J.K. Anozie, N.J. Emerenini, N.U. Okoro, “Bleaching Efficiency of Ortho-Phosphoric Acid Activated Kaolin Clay Sample on Crude Palm Oil Colour Pigment Removal,” International Journal of Scientific Research in Chemical Sciences, Vol.7, Issue.6, pp.12-20, 2020.

MLA Style Citation: R.E. Nnam, J.K. Anozie, N.J. Emerenini, N.U. Okoro "Bleaching Efficiency of Ortho-Phosphoric Acid Activated Kaolin Clay Sample on Crude Palm Oil Colour Pigment Removal." International Journal of Scientific Research in Chemical Sciences 7.6 (2020): 12-20.

APA Style Citation: R.E. Nnam, J.K. Anozie, N.J. Emerenini, N.U. Okoro, (2020). Bleaching Efficiency of Ortho-Phosphoric Acid Activated Kaolin Clay Sample on Crude Palm Oil Colour Pigment Removal. International Journal of Scientific Research in Chemical Sciences, 7(6), 12-20.

BibTex Style Citation:
@article{Nnam_2020,
author = {R.E. Nnam, J.K. Anozie, N.J. Emerenini, N.U. Okoro},
title = {Bleaching Efficiency of Ortho-Phosphoric Acid Activated Kaolin Clay Sample on Crude Palm Oil Colour Pigment Removal},
journal = {International Journal of Scientific Research in Chemical Sciences},
issue_date = {12 2020},
volume = {7},
Issue = {6},
month = {12},
year = {2020},
issn = {2347-2693},
pages = {12-20},
url = {https://www.isroset.org/journal/IJSRCS/full_paper_view.php?paper_id=2217},
publisher = {IJCSE, Indore, INDIA},
}

RIS Style Citation:
TY - JOUR
UR - https://www.isroset.org/journal/IJSRCS/full_paper_view.php?paper_id=2217
TI - Bleaching Efficiency of Ortho-Phosphoric Acid Activated Kaolin Clay Sample on Crude Palm Oil Colour Pigment Removal
T2 - International Journal of Scientific Research in Chemical Sciences
AU - R.E. Nnam, J.K. Anozie, N.J. Emerenini, N.U. Okoro
PY - 2020
DA - 2020/12/31
PB - IJCSE, Indore, INDIA
SP - 12-20
IS - 6
VL - 7
SN - 2347-2693
ER -

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Abstract :
Vegetable oil is one of the basic food items widely consumed by every human being in the universe and therefore its quality should be good enough so that it accounts for healthy life. The purity characteristics desirable in edible oil, such as light colour, bland taste and a good oxidative stability of locally produced palm oil is obtained by refining. To this end, the bleaching efficiency of locally produced palm oil using Ortho-phosphoric acid kaolin clay sourced from Ogbagu Ndemiyi Unwana, in Afikpo North L. G. A. of Ebonyi State, Nigeria, as the absorbent is investigated in this research. The clay was activated at different acid concentrations to improve its adsorptive capacity. To study the ability or performance of the acid-treated clay to remove colour pigment from locally produced oil, four process variables namely, acid concentration, process contact time, adsorbent dosages and temperature were investigated. The variation of the process variables were in the order acid concentrations (1M, 2M, 3M, 5M); adsorbent dosages (1.0- 3.0g); reaction temperature (30-120?); and reaction time (5-60minutes). The results show that the bleaching efficiency of the activated clay increases with increase in acid concentration, temperature, contact time, temperature and adsorbent dosage. For acid concentrations, the bleaching efficiency increased with increase in acid concentration. However, there was only a slight difference between the bleaching efficiency of kaolin clay activated with 3M and that activated with 5M. Therefore, activated kaolin clay of 3M and 5M can be used with little or no difference in the bleaching efficiency. The result also shows that the optimal contact time for the bleaching process is 30 minutes at 120? for a dosage of 3g.

Key-Words / Index Term :
Acid activation; kaolin clay; Crude palm oil; Acid concentrations; Adsorption; Ndemiyi; Unwana

References :
H. Noyan, M. Önal, and Y. Sar?kaya, “The Effect of Sulphuric Acid Activation on the Crystallinity, Surface Area, Porosity, Surface acidity, and Bleaching power of a Bentonite”, Food chemistry. 105(1): p. 156-163. 2007.
M. Analava and M. Sutapa, “Health effects of Palm Oil”. Journal of Human Ecology, 26(3):197-203, 2009.
S.M.Silva, K.A. Sampaio, R. Ceriani, R. Verh_e, C. Stevens, W. De Greyt, A. J. A. Meirelles, “Effect of Type of Bleaching Earth on the Final Color of Refined Palm Oil”, LWT -Food Sci. Technol. 59 (2), 1258-1264, 2014.
P. T. Gee, “Analytical characteristics of crude and refined palm oil and fractions”, European Journal of Lipid Science and Technology, 109(4), 373-379, 2007.
V. Gibon, W. De Greyt, and M. Kellens, “Palm oil Refining”, European Journal of Lipid Science and Technology, 109(4), 315-335, 2007.
Y. Basiron, “Palm Oil, in Bailey’s Industrial Oil and Fat Products”, edited by Y.H. Hui, , 2, 271 – 373, 1996.
R.S. Pohndorf, T.R.S. Cadaval Jr, L.A.A., “Pinto. Kinetics and thermodynamics adsorption of carotenoids and chlorophylls in rice bran oil bleaching”, Journal of Food Engineering 185: 9-16, 2016.
F. Kreps, L. Vrbikov_a, S. Schmidt, “Influence of Industrial Physical Refining on Tocopherol, Chlorophyll and Beta-Carotene Content in Sunflower and Rapeseed Oil”, Eur. J. Lipid Sci. Technol. 116, 1572-1582, 2014.
F. Marrakchi, K. Kriaa, B. Hadrich, N. Kechaou, “Experimental investigation of processing parameters and effects of degumming, neutralization and bleaching on lampante virgin olive oil`s quality”, Food Bioprod. Process. 94, 124-135, 2015.
E.R. Baümler, G.H. Crapiste, A.A. Carelli, “Sunflower-oil wax reduction by seed solvent washing”, J. Am. Oil Chem. Soc. 84, 603-608, 2007.
V.R. Pestana-Bauer, R.C. Zambiazi, C.R.B. Mendonça, M. Beneito-Cambra, G. Ramis-Ramos, “?-oryzanol and Tocopherol Contents in Residues of Rice Bran Oil Refining”, Food Chem. 134, 1479-1483, 2012.
J. T. Nwabanne and F. C. Ekwu, “Decolourisation of Palm Oil by Nigerian Local Clay: A Study of Adsorption Isotherms and Bleaching Isotherms”, International Journal of multidisciplinary Sciences and Engineering, 4(1): 308 – 318, 2013.
M.H.L. Ribeiro, P.A.S. Lourenço, J.P. Monteiro, S. Ferreira-Dias, “Kinetics of selective adsorption of impurities from a crude vegetable oil in hexane to activated earths and carbons”, Eur. Food Res. Technol. 213, 132-138, 2001.
G.E. Christidis, & S. Kosiari, “Decolourization of Vegetable Oils: A study of the Mechanism of Adsorption of ?-carotene by Acid activated Bentonite form Cyprus”, Clays Miner., 51, 327 – 333, 2003.
E.L. Foletto, C. Volzone, and L.M. Porto, “Clarification of cotton seed oil: how structural properties of treated bentonites by acid affect bleaching efficiency”, Latin American Applied Research. 36, 37 – 40, 2006.
T. Permana, E. Noor and Y. Arkeman, “Evaluation of Kinetic Models of Beta-Carotene Adsorption from Palm Oil onto Bentonite”, International Journal Of Scientific & Technology Research VOLUME 7, ISSUE 4 , 23-31, 2018.
E. Ujeneza, “Optimization of Acid Activation and Bleaching Performance of Local Bentonite Clay”, University of Nairobi. 2014.
A.M. Bello, V.O. Ajibola and S.O. Idris, “Activation of Clay Sample from Zaria L.G.A. of Kaduna State and Testing its Bleaching Performance on Groundnut Oil, Palm Oil and Cottenseed Oil”, Chemsearch Journal 2(2): 36 – 38, 2011.
R. Kamga, G. J. Kayem and P. G. Rouxhet, “Adsorption of Goddypol from Cotton Seed Oil on Oxide”, J. Colloid interface Sci., 232,198-206, 2000
P. Falaras, I. Kovais, F. Lezou and G. Seiragakis, “Cotton seed oil bleaching by acid activated montmorillonite”, Clay minerals, vol. 3, no. 4, pp.221 -232, 1999.
B. A. Akinwande, T. O. Salawudeen, A. O. Arinkoola and M. O. Jimoh, “Effect of Activation on Clays and Carbonaceous Materials in Vegetable Oil Bleaching: State of Art Review British Journal of Applied Science & Technology 5(2): 130-141, 2015.
A. Khan, “Bleaching of Vegetable Oil using Organic Acid Activated Fuller’s Earth (Bentonite Clay)”, Global Journal of Researches in Engineering (C) Volume 15 Issue 2 Version 1.0, 2015.
R. Berbesi, “Achieving Optimal Bleaching performance”, Oil Mill Gazetteer, 112 1-5, 2006.
S. I. Mustapha, A. A. Mohammed, A. Y. Zakari and H. A., “Mohammed. Performance Evaluation of Local Clays from Northern Nigeria for the Refining of Palm Oil”, Journal of Chemical Engineering and Materials Science. Vol. 4(5), pp. 58-66, 2013.
Okeke J. A., “Adsorption Bleaching of Sheanut oil”, Proceeedings of N. S. E., pp. 14-19, (1990).
M. N. Danjuma, “Performance of Locally Prepared Adsorbent”, Proceedings of National Engineering Conference of the College of Engineering, Kaduna Polytechnic. (2001).
J. T. Nwabanne, C. E. Onu. and O. C. Nwankwoukwu, “Equilibrium, Kinetics and Thermodynamics of the Bleaching of Palm Oil Using Activated Nando Clay”, Journal of Engineering Research and Reports 1(3): 1-13, 2018
B.A. Akinwande, T.O. Salawudeen, A.O. Arinkoola and M.O. Jimoh, “A Suitability Assessment of Alkali Activated Clay for Application in Vegetable Oil Refining”, International Journal of Engineering and Advanced Technology Studies. Vol.2, No.1, pp.1-12, 2014
E. Balan, T. Allard, B. Boizot, G. Morin and J.P. Muller, “Structural Fe3+ in Natural Kaolinites: New Insights from Electron Paramagnetic Resonance Spectra Fitting at X and Q-band Frequencies”, Clays and Clay Minerals 47, 605-616, 1999.
R. O. Ajemba and O. D. Onukwuli, “Adsorptive Removal of Colour Pigment from Palm Oil Using Acid Activated Nteje Clay: Kinetics, Equilibrium and Thermodynamics”, Physicochem. Probl. Miner. Process 49(1):369-381, 2012.
M. A. Usman, V. I. Ekwueme, T. O. Alaje, and A. O.Mohammed, “Characterization, Acid Activation, and Bleaching Performance of Ibeshe Clay, Lagos, Nigeria”, International Scholarly Research Network ISRN Ceramics Volume 2012, Article ID 658508, 5 pages doi:10.5402/2012/658508.
A. O. Oboh, O.C. Aworhi, and O. K. Agagu, “The Use of Nigerian Clays in Vegetable Oil Refining: Evaluation of Some Nigerian Clays as Potential Bleaching Earths”, Nigerian Food Journal, vol. 5, pp. 42–51, 1987.
C. E. Onu and J. T. Nwabanne. Adsorption studies on the Removal of Eriochrome Black-T from aqueous solution using Nteje clay. SOP Transactions on Applied Chemistry. 1(2):14–25, 2014.
B.J. Nde-Aga, R. Kamga, and J. P. Nguetnkam, “Adsorption of Palm Oil Carotene and Free Fatty Acid onto Acid Activated Camerounian Clays”, J. Applied Science, 7 (17), 2462- 2467, 2007.
A. C. Etuk, "Comparative analysis of acid activated Nteje clay and two commercially available adsorbents (fuller’s earth and activated carbon)", 2015.
L.F. Athy, “Density, Porosity and Compactation of Sedimentary rocks”, Bull. Amer. Assoc. Petrol. Geol. v. 14, pp. 1-24, 1930.
R. O Ajemba and O. D. Onukwuli, “Accessing influence of hydrochloric acid leaching on structural changes and bleaching performance of Nigerian clay from Udi. Physicochemical Problems of Mineral Processing. 50(1):349-358, 2013.
R. O. Ajemba, , P. K. Igbokwe and O. D. Onukwuli, “Kinetics, Equilibrium, and Thermodynamics Studies of Colour Pigment Removal from Palm Oil using Activated Ukpor Clay”, Archives of Applied Science Research, 4(5):1958-1966.
M.I. Dias, B. M. Suarez, S. Prates and J. M. Martin, “Characterization and acid activation of Portuguese special clay”, Appl. Clay Sci. 18:537-549, 2003.
R. O. Ajemba and O. D. Onukwuli, “Accessing influence of hydrochloric acid leaching on structural changes and bleaching performance of Nigerian clay from Udi”, Physicochemical Problems of Mineral Processing, 50(1):349-358, 2013.
M. A. Usman, O. Oribayo, A. A. Adebayo, “Bleaching of Palm Oil by Activated Local Bentonite and Kaolin Clay from Afashio, Edo – Nigeria”, Chemical and Process Engineering Research. 10:1-12, 2013.
A. R. Mohammed, S. M. Ruhul Amin, A. M. Shafiqul Alam, “Removal of Methylene Blue from Waste Water using Activated Carbon Prepared from Rice Husk”, Dhaka Un. V. J. Sci. 60(2):185-189, 2012.

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