X-ray diffraction and X-ray K-absorption near edge studies of Copper (II) Micro cyclic Carbamide complexes

D.Bhalse ¹ , Rashmi Kame² , Pramod Malviya³ , Pradeep Sharma⁴ , A.Mishra ⁵

Section:Research Paper, Product Type: Isroset-Journal
Vol.2 , Issue.9 , pp.1-5, Oct-2016

Online published on Oct 31, 2016

Copyright © D.Bhalse, Rashmi Kame, Pramod Malviya, Pradeep Sharma , A.Mishra . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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Abstract :
Synthesis of metal complexes [Cu (Carbamide)] (X = Br, Cl, NO3, SO4,CH3COO) by the chemical root method. The XRD data have been recorded at DAE, IUC Indore.XANES spectra have been recorded at the K-edge of Cu using the dispersive beam line at 2.5GeV Indus-2 synchrotron radiation source RRCAT (Raja Ramanna Center for Advance Technology), Indore, India. XRD and XANES data have been analysed using the computer software Origin 8.0 professional and Athena. X-ray diffraction studies of all the complexes are indicative of their crystalline nature. The crystalline size of the samples is estimated using the Scherer’s formula. The values of the chemical shifts suggest that copper is in oxidation state +2 in all of the complexes.

Key-Words / Index Term :
Cu (II) Carbamide complex, XRD, XANES

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