Full Paper View Go Back

Effect of Annealing Temperature on Structural and Optical properties of Mn doped SnO2 Thin Films Prepared by Sol-Gel Technique

Sunaina 1 , Parikshit Sharma2 , Prianka Sharma3

Section:Research Paper, Product Type: Isroset-Journal
Vol.7 , Issue.2 , pp.99-107, Apr-2019


CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v7i2.99107


Online published on Apr 30, 2019


Copyright © Sunaina, Parikshit Sharma , Prianka Sharma . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

View this paper at   Google Scholar | DPI Digital Library


XML View     PDF Download

How to Cite this Paper

  • IEEE Citation
  • MLA Citation
  • APA Citation
  • BibTex Citation
  • RIS Citation

IEEE Style Citation: Sunaina, Parikshit Sharma , Prianka Sharma, “Effect of Annealing Temperature on Structural and Optical properties of Mn doped SnO2 Thin Films Prepared by Sol-Gel Technique,” International Journal of Scientific Research in Physics and Applied Sciences, Vol.7, Issue.2, pp.99-107, 2019.

MLA Style Citation: Sunaina, Parikshit Sharma , Prianka Sharma "Effect of Annealing Temperature on Structural and Optical properties of Mn doped SnO2 Thin Films Prepared by Sol-Gel Technique." International Journal of Scientific Research in Physics and Applied Sciences 7.2 (2019): 99-107.

APA Style Citation: Sunaina, Parikshit Sharma , Prianka Sharma, (2019). Effect of Annealing Temperature on Structural and Optical properties of Mn doped SnO2 Thin Films Prepared by Sol-Gel Technique. International Journal of Scientific Research in Physics and Applied Sciences, 7(2), 99-107.

BibTex Style Citation:
@article{Sharma_2019,
author = {Sunaina, Parikshit Sharma , Prianka Sharma},
title = {Effect of Annealing Temperature on Structural and Optical properties of Mn doped SnO2 Thin Films Prepared by Sol-Gel Technique},
journal = {International Journal of Scientific Research in Physics and Applied Sciences},
issue_date = {4 2019},
volume = {7},
Issue = {2},
month = {4},
year = {2019},
issn = {2347-2693},
pages = {99-107},
url = {https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=1307},
doi = {https://doi.org/10.26438/ijcse/v7i2.99107}
publisher = {IJCSE, Indore, INDIA},
}

RIS Style Citation:
TY - JOUR
DO = {https://doi.org/10.26438/ijcse/v7i2.99107}
UR - https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=1307
TI - Effect of Annealing Temperature on Structural and Optical properties of Mn doped SnO2 Thin Films Prepared by Sol-Gel Technique
T2 - International Journal of Scientific Research in Physics and Applied Sciences
AU - Sunaina, Parikshit Sharma , Prianka Sharma
PY - 2019
DA - 2019/04/30
PB - IJCSE, Indore, INDIA
SP - 99-107
IS - 2
VL - 7
SN - 2347-2693
ER -

509 Views    175 Downloads    81 Downloads
  
  

Abstract :
Mn doped SnO2 thin films were prepared by sol-gel dip coating technique. The deposited films on glass substrate were annealed at 300oC, 400oC and 500oC. The effect of annealing temperature on the structure and optical properties of the Mn-SnO2 thin films have been studied by X-ray diffraction and UV-Vis spectrophotometry. X-ray diffraction studies shows the tetragonal rutile structure of SnO2 with no additional phases of SnO2. Various parameters like crystallite size, lattice constants, dislocation density and microstrain have been calculated and found to vary with annealing temperature. The optical transmission spectra shows a red shift in the position of absorption edge towards higher wavelength for Mn- doped thin films but as the annealing temperature increases, the absorption edge shifts toward lower wavelengths. The optical constants and the optical parameters were determined by the spectral transmittance data.

Key-Words / Index Term :
Diluted Magnetic Semiconductors, Mn-SnO2 thin films, Sol-Gel Dip Coating method, Annealing Temperature, Band Gap, Urbach’s Energy

References :
[1]. T.A. Dar, A. Agrawal, P. Sen, “Role of Ni Doping on structural, Electronic and Transport Properties of ZnO Thin Films”, International Journal of Scientific Research in Physics and Applied Sciences. Vol. 3, pp 2348-3423, 2015.
[2]. S.J. Pearton, W.H. Heo, M. Ivill, D.P. Norton, T. Steiner, “Dilute Magnetic Semiconducting Oxides”, Semicond.Sci. Technol. Vol. 19, No. 59, 2004.
[3]. Y. Xu, Y. Tang, C. Li, G. Cao, W.Ren, H.Xu, Z. Ren, “Synthesis and Room-Temperature Ferromagnetic Properties of Single-Crystalline Co-doped SnO2 Nanocrystals Via a High Magnetic Field”, J. Alloys Compd. Vol. 481, pp 837-840, 2009.
[4]. S. SujathaLekshmy, G.P. Daniel, K. Joy, “Microstructure and Physical Properties of Sol-Gel Derived SnO2: Sb Thin films for Optoelectronic Applications”, Appl. Surf. Sci. Vol. 274, pp 95-100, 2013.
[5]. S. SujathaLekshmy, K. Joy, “SnO2 Thin Films Doped with Indium Prepared by Sol-Gel Method: Structure, Electrical and Photolumininescence Properties”, J. Sol-Gel Sci. Technol. Vol. 67, pp 29-38, 2013.
[6]. S. SujathaLekshmy, L.V. Maneeshya, P.V. Thomas, K. Joy, “Intense UV Photolumininescence Emission at Room Temperature in SnO2 Thin Films”, Indial J. Phys. Vol. 87, pp 33-38, 2013.
[7]. C. Drake, S. Seal, “Band Gap Energy Modifications Observed in Trivalent In Substituted Crystalline SnO2”, Appl. Phys. Lett. Vol. 90, No. 233117, 2007.
[8]. C. Kilic, A. Zunger, “Origins of Coexistence of Conducting and Transparency in SnO2”, Phys. Rev. Lett. Vol. 88, No. 95501, 2002.
[9]. S.C. Erwin, L. Zu, M.I. Haftel, A.L. Efros, T.A. Kennedy D.J. Norris, “Doping Semiconductor Nanocrystals”, Nature Vol. 436, No. 03832, pp 91-96, 2005.
[10]. D.J. Norris, A.L. Elfros, S.C. Erwin, “Doped Nanocrystals”, Science Vol. 319, No. 5871, pp 1776-1785, 2008.
[11]. I.J. Berlin, J.S. Lakshmi, S. SujathaLekshmy, G.P. Daniel, P.V. Thomas K. Joy, “Effect of Sol Temperature on the Structure, Morphology, Optical and Photoluminescence Properties of Nanocrystalline Zirconia Thin Films”, J. Sol-Gel Sci. Technol. Vol. 58, pp 669-676. 2011.
[12]. K. Joy, S. SujathaLekshmy, P.B. Nair, G.P. Daniel, “Band gap and Superior Refractive Index Tailoring Properties in Nanocomposite Thin Film Achieved through Sol-Gel Co-deposition Method”, J. Alloy. Compd. Vol. 512, pp 149-155, 2012.
[13]. J.M.D. Coey, A.P. Douvalis, C.B. Fitzgerald, M. Venkatesan, “Ferromagnetism in Fe-doped SnO2 Thin Films”, Appl. Phy. Lett. Vol. 84, pp 1332-1334, 2004.
[14]. N.H. Hong, J. Sakai, W. Prellier, A. Hassini, “Transparent Cr-doped SnO2 Thin Films: Ferromagnetism beyond Room Temperature with a Giant Magnetic Moment”, J. Phys. Condens. Matter Vol. 17, pp 1697-1702, 2005.
[15]. X.F. Liu, W.M. Gong, J. Iqbal, B. He, R.H. Yu, “Structural Defects Mediated Room Temperature Ferromagnetism in Co-doped SnO2 Insulating Films, Thin Solid Films”, Vol. 517, pp 6091-6095, 2009.
[16]. M.M. Bagheri-Mohagheghi, N. Shahtahmasebi, M.R. Alinejad, A. Youssefi, M. Shokooh-Saremi, “Fe-doped SnO2 Transparent Semiconducting Thin Films Deposited by Spray Pyrolisis Technique: Thermoelectric and p-type Conductivity Properties”, Solid State Sci Vol. 11, pp 233-239, 2009.
[17]. K. Galatsis, L. Cukrov, W. Wlodarski, P. McCormick, K.Kalantarzadeh, E. Comini, G. Sberveglieri, “p- and n-type Fe-doped SnO2 Gas Sensors Fabricated by the Mechanochemical Processing Technique”, Sens. Actuators B. Chem. Vol. 93, pp 562-565, 2003.
[18]. M.M. Bagheri-Mohagheghi, M. Shokooh-Saremi, “The Electrical, Optical, Structural and Thermoelectrical Characterization of n- and p-type Co-doped SnO2 Transparent Semiconducting Films Prepared by Spray Pyrolysis Technique”, Physica B Vol. 19, pp 4205-4210, 2010.
[19]. A. Kaushal, P. Bansal, R. Vishnoi, N. Choudhary, D. Kaur, “Room Temperature Ferromagnetism in Sn1-xMnxO2 Nanocrystalline Thin Films Prepared by Ultrasonic Spray Pyrolysis”, Physica B Vol. 404, pp 3732-3738, 2009.
[20]. F. Gu, S.F. Wang, M.K. Lu, G.J. Zhou, D. Xu and D. R. Yuan, “Photoluminescence Properties of SnO2 Nanoparticles Synthesized by Sol-Gel Method”, J. Phys. Chem. B Vol. 108, No. 35, pp 8119-8123, 2004.
[21]. H. Kimuraa, T. Fukumuraa, H. Koinuma, M. Kawasaki, “Fabrication and Characterization of Mn-doped SnO2 Thin films”, Physica E Vol. 10, pp 265-267, 2001.
[22]. R. Brahama, M.G. Krishna, A.K. Bhatnagar, “Optical, Structural and Electrical Properties of Mn-doped Tin Oxide Thin Films”, Bull. Mater. Sci Vol. 29 pp 317-322, 2006.
[23]. Y. Xiao, Sh.Ge, Li. Xi, Y.Zuo, X. Zhou, B. Zhang, L. Zhang, Ch. Li, X. Han, Zh. Wen, “Optical and Ferroelectric Properties of KxNa1-xBa2Nb5O15 ”, Appl. Surf. Sci. Vol. 2547, pp 459-463, 2008.
[24]. E.G. Birgin, I. Chambouleyron, J.M. Martinez, “Determination of Thickness and Optical Constants of Amorphous Silicon Films from Transmittance Data”, J. Comput. Phys. Vol. 77, No. 2133, 2000.
[25]. J. Tauc, “Amorphous and Liquid Semiconductor (Plenum, New York, 1974).
[26]. M. DiDomenico, S.H. Wemple, “Oxygen-Octahedra Ferroelectrics I, Theory of Electro-Optical and Nonlinear Optical Effects”, J. Appl. Phys. Vol. 40, pp 720-734, 1969.
[27]. M.M. Bagheri-Mohagheri, M. Shokooh-Saremi, “Electrical, Optical and Structural Properties of Li-doped SnO2 Transparent Conducting Films Deposited by the Spray-Pyrolysis Technique: A Carrier-Type Conversion Study”, Semicond. Sci. Technol. Vol. 19 No. 6, pp 764-769, 2004.
[28]. Z.M. Tian, S.L. Yuan, J.H. He, P. Li, S.Q. Zhang, C.H. Wang, Y.Q. Wang, S.Y. Yin, L. Liu, “Structural and Magnetic Properties in Mn Doped SnO2 Nanoparticles Synthesized by Chemical Co-Precipitation Method”, J. Alloys Compd. Vol. 466, No.1, pp 26-30, 2008.
[29]. B.D. Cullity, S.R. Stock, Elements of X-Ray Diffraction, 3rd Edn. Prentice Hall, Upper Saddle River (2001) 388.
[30]. S. Prabhakar, M. Dhanam, “Cds Thin Films from Two Different Chemical Baths- Structural and Optical Analysis”, J. Cryst. Growth Vol. 285, pp 41-48, 2005.
[31]. F.E. Ghodsi, J. Mazloom, “Optical, Electrical and Morphological Properties of p-type Mn-doped SnO2 Nanostructured Thin Films Prepared by Sol-Gel Process”, Appl. Phys. A 108 (2012) 693-700.
[32]. Sathyaseelan, K. Senthilnathan, T. Alagesan, R. Jayavel, K. Sivakumar, “Formation of Mn doped SnO2 Nanoparticles Via the Microwave Technique: Structural, Optical and Electrical Properties”, Mater. Chem. Phys. Vol. 124, pp 1046-1050, 2010.
[33]. A. Bouaine, N. Brihi, G. Schmerber, C. Uihaq-Bouillet, S. Colis, A. Dinia, “Structural, Optical and Magnetic Properties of Co-doped SnO2 Powders Synthesized by the Coprecipitation Technique”, J.Phys. Chem. C Vol. 111, pp 2924-2928, 2007.
[34]. T.N. Soitah, C. Yang, L. Sun, “Structural, Optical and Electrical Properties of Fe-doped SnO2 Fabricated by Sol-Gel Dip Coating Technique”, Mater. Sci. Semicond. Process, Vol. 13, pp 125-131, 2010.
[35]. M.M. Abd El. Raheem, “Optical Properties of GeSeTI Thin Films”, J. Phys.: Condens. Matter Vol. 19, No. 216209, 2007.
[36]. L. Wang, L. Meng, V. Teixeira, S. Song, Z. Xu, X. Xu, “Structural and Optical Properties of ZnO: V Thin Films with Different Doping Concentrations”, Thin Solid Films Vol. 517, pp 3721-3725, 2009.
[37]. D.L. Wood, J. Tauc, “Weak Absorption Tails in Amorphous Semiconductors”, Phys. Rev. B Vol. 5, pp 3144-51, 1972.

Authorization Required

 

You do not have rights to view the full text article.
Please contact administration for subscription to Journal or individual article.
Mail us at  support@isroset.org or view contact page for more details.

Go to Navigation