Growth and Characterization Studies on Nicotinic Acid Doped Kdp Crystals

M. Navinaa¹ , M. Sornambola² , S. Gowrib³ , J. Aarthib⁴ , P. Evangelin Teresaa⁵

Section:Research Paper, Product Type: Isroset-Journal
Vol.7 , Issue.3 , pp.156-166, Jun-2019

CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v7i3.156166

Online published on Jun 30, 2019

Copyright © M. Navinaa, M. Sornambola, S. Gowrib, J. Aarthib , P. Evangelin Teresaa . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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Abstract :
In the present work the growth of potassium dihydrogen phosphate crystal doped with nicotinic acid at various concentrations is reported. KDP is a well –known optical material having different applications in electro-optics and laser technology. Nicotinic acid doped KDP crystal is grown using slow solvent evaporation technique. The doping of nicotinic acid at various concentrations was successively achieved in KDP crystal and confirmed by Fourier transform infrared spectroscopy analysis. The modification of optical transmittance and other optical constants of KDP crystal due to the doping of nicotinic acid have been investigated by means of UV-visible spectral analysis. The dielectric behavior of the sample has been studied. The variation of the dielectric loss with frequency of the applied field is reported.

Key-Words / Index Term :
FTIR, dielectric studies, antimicrobial studies UV-visible spectral analysis

References :
[1]. P.Santhana Raghavan, P.Ramaswamy ‘Recent trends in crystal growth technology’, PINSA , 68; No 3 may (2002).
[2]. R. Dillip, C.Madhukar Reddy, B.Deva Prasad Raju ‘Growth and characterization of non linear optical material’, J.Minerals and materials characterization and engineering,10-12, 1103-1110, (2002).
[3]. E.D.Yakushkin, E.P.Efremova, A.I.Baranova, ‘Growth conditiond and electrical properties of KDP crystals: II Dielectric permittivity measurements’, crystallography reports, 46-5,904-908, (2001).
[4]. T.Prasanyaa and M.Haris , ‘Growth and chacterization of semi organic NL0 L-arginine trifluroacetate 9LATF added KDP single crystals’, Archives of physics Research, 2(4), 60-66, (2011).
[5]. M.Iyanar, J.Thomas Joseph Prakash, C.Muthammichelvan and S.Ponnusamy, ‘synthesis, growth, and characterization studies of the semi organic nonlinear optical single crystal of gamma glycine’, Journel of physics sciences, 235-244, 13, (2009).
[6]. K.D.Parikh, B.B. Pakekh, M.J.Joshi, ‘structural, SHG and dielectric study of L-tryptophan doped KDP crystals’, Proc. International conference on materials and characterization techniques, VIT university, vellore 1559-1562, (2014).
[7]. B.Deepa and P.Philominathan , ‘Enchanced NLO and antibacterial properties of nicotinic acid doped KDP crystals : synthesis, growth and characterization’, Materials research innovation, (2016).
[8]. https://en.m.wikipedia.org>wiki> Niacin.
[9]. V.Sangeetha, K.Gayathiri, P. Krishnan, N.Sivakumar and N.Kanaganathan ‘Growth, optical, thermal, dielectric and microhardness characterizations of melaminimum bis (trifluroacetate) trihydrate single crystal’, J.cryst.growth, 389,30-38, (2014).
[10]. Z.Delci, D.shyamala, S.Karuna, and A.Thayumanavan. ‘Optical characterization studies on boron doped KDP crystals’, Archives of physics research, 3(5): 346-353, 2012.
[11]. H.Huang, X.Yang, Carbohyder.Res. 339, 574, (2004).
[12]. Salah Sedarous, J.Anand Subramony , Bart Kahr, ‘Structure and optical characterization of Rochelle salt dye inclusion crystals and fluorescence detection of their phase transitions’ ferroelectric, 191, 301-306, (1997).
[13]. A.Arunkumar, P. Ramaswamy, K. Vishnu, M.K. Jayaraj, ‘ Growth, structural, thermal, optical, and electrical properties of potassium succinate-succinic acid crystal’, J.Mater. Sci. 49, 3598-3607 (2014).
[14]. C.L. Amiot, S. Xu, S. Liang, L.Pan, J.X. Zhao, ‘ Near –infrared fluorescent materials for sensing of biological targets’, Sensors 8, 3082-3105 (2008).
[15]. V.Revathi, V.Rajendran, ‘synthesis, Growth and characterization of semi organic zinc(tris) thiourea chloride crystals’, Recent Research in science and technology., 4(2), 38-41, (2012).
[16]. U.Krunanithi, S.Arulmozhi and J.Madhavan, ‘structural, optical and dielectric studies on pure and doped L-Alanimium Maleate single crystals’, IOSR Journal of applied physics, 1(2), 19-23, (2012).
[17]. R.Anandhakumari and R.Chandramani, ‘Electrical conductivity and dielectric measurements in Au+ doped /undoped KDP crystals with KCL and NaCl magnetic, as additives’, Indian Journal of applied physics , 1(2), 19-23, (2012).
[18]. P.R.Modiya and C.N patel ‘synthesis and screening of antibacterial and fungal activity of 5-chloro-1, 3-benzoxal-2(3h)-0ne derivatives org’, med. Chem.lett.,2,29, (2012).
[19]. S.M.Roy, M.R.Sundarsanakumar, V.S.Dhanya, S.Suma and M.R.Prathapachandra kurup ‘ crystal growth, spectral, Antibacterial and antifungal studies of co(II)and Ni(II) complexes of 4-nitrobenzoic Acid’,J.Korean chem. .Soc.,58,(3),258-266,(2014).
[20]. H.Liu, W.Yang, W.Zhou,Y.Xie and M.Li: ‘Crystal structures and antimicrobial activities of copper (2) complexes of fluorine-containing thioureido ligands’,Inorg.Chim. Acta.405, (24),387-394,(2013).