Synthesis and Spectroscopic Characterization-XRD of Mixed Ligand Cu(II) Complexes of 8 - Hydroxyquinoline and o-hydroxybenzylidene-1- phenyl-2, 3-dimethyl- 4 -amino- 3 -pyrazolin- 5 -on

Pradeep Sharma¹ , Jaishree Bhale² , A.Mishra ³ , Pramod Malviya⁴ , Seema Upadhyay⁵

Section:Research Paper, Product Type: Isroset-Conference
Vol.3 , Issue.1 , pp.19-21, Jan-2015

Online published on Feb 28, 2015

Copyright © Pradeep Sharma, Jaishree Bhale,A.Mishra,Pramod Malviya,Seema Upadhyay . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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Abstract :
In this paper new mixed ligand Cu(II) complexes containing schiff base and 8-hydroxyquinoline with the general formula [Cu(L)(Q)] where L= o-hydroxybenzylidene-1-phenyl-2,3-dimethyl-4-amino-3-pyrazolin-5-on and Q=8-hydroxyquinoline were synthesized. The mixed ligand was prepared by chemical root procedure. The resulting product was found to be solid which have been characterized using XRD spectroscopy. The mixed ligand act as primary ligand while sulphate, nitrate, acetate and bromide act as secondary ligand. The data obtained has been preceding using XRD data analysis program Origin 6.0 Professional. From the experimental measurements, various parameters- lattice parameter and particle size have been estimated. Particle size is found to be in the range of 0.07- 0.13 nanometer. The XRD analysis revealed the crystalline nature of all the complexes.

Key-Words / Index Term :
XRD, 8-Hydroxyquinoline Complexes,Schiff base Complexes, o-Hydroxybenzylidene-1-phenyl-2,3-dimethyl-4- amino-3-pyrazolin-5-on Complexes, Mixed ligand Complexes

References :
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