X-ray Absorption Near Edge Structure Studies of Transition Metal Complexes of O-Phenylenediamine and Substituted Aniline Ligand

Kamaljeet S. Sura¹ , A. Mishra² , S. Patidar³ , S. Mohammad⁴

1. School of Physics, DAVV, Indore (M.P), India.
2. School of Physics, DAVV, Indore (M.P), India.
3. School of Physics, DAVV, Indore (M.P), India.
4. School of Physics, DAVV, Indore (M.P), India.

Correspondence should be addressed to: kamaljeetsura@gmaill.com.

Section:Research Paper, Product Type: Isroset-Journal
Vol.6 , Issue.3 , pp.40-44, Jun-2018

CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v6i3.4044

Online published on Jun 30, 2018

Copyright © Kamaljeet S. Sura, A. Mishra, S. Patidar, S. Mohammad . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

View this paper at   Google Scholar | DPI Digital Library

XML View     PDF Download

How to Cite this Paper

408 Views    277 Downloads    117 Downloads

Abstract :
The present paper deals with the synthesis of transition metal complexes of Copper by chemical rout method. The complexes have been synthesized by condensation of o-phenylenediamine, diethyl malonate and diazonium ion in the ethanolic medium, through refluxing with Cu (II) metal salt. Synthesized metal complexes were characterized by X-ray diffraction (XRD) and studied by X-ray absorption structure (XAS) spectroscopy. The XAS technique includes XANES (X-ray Absorption near Edge structure) and EXAFS (Extended X-ray Absorption Fine Structure) spectroscopy. XANES spectra have been recorded at the K-edge of Cu using the dispersive EXAFS (DEXAFS) beam line at 2.5GeV Indus-2 synchrotron radiation source RRCAT, Indore, India. The XANES data have been analysed using the computer software Athena. These have been used to determine the chemical shift, edge width, and nature of complexes. XRD analysis shows that sample is crystalline in nature. The XRD pattern is made by using Bruker D-8 advance instrument.

Key-Words / Index Term :
XRD, XANES, chemical shift,edge width

References :
R.H. Holm, G.W. Everett, A. Chakravorty, “Prog. Inorg. Chem. 7” (1966) 83
[2] W. Zhang, J.L. Loebach, S.R. Wilson, E.N. Jacobsen, “J. Am. Chem. Soc”. 112 (1990) 2801
[3] R.D. Jones, D.A. Summerville, F. Basolo, “Chem. Rev. “79 (1979)139
[4] A. Vogler, H. Kunkely, “Coord. Chem. Rev.” 177 (1998) 81.
[5] J.-L. Serrano, L. Oriol, “Adv. Mater.” 7 (1995) 365.
[6] L. Mao, K. Yamamato, W. Zhou, L. “Jin, Electroanalysis” 12 (2000) 72.
[7] K. Chichak, U. Jacquembard, N.R. Branda, “Eur. J. Inorg. Chem.” 8 (2002) 357.
[8] L.H. Vogt, H.M. Faigenbaum, S. Wiberly, “Chem. Rev.” 63 (1963) 269
[9] S.J. Gruber, C.M. Harris, E. Sinn, “J. Inorg. Nucl. Chem.” 30 (1968) 1805
[10] Thompson K H, B¨ohmerle K, Polishchuk E, Martins C, Toleikis P, Tse J, Yuen V,Mcneill J H and Orvig C 2004 “Journal of Inorganic Biochemistry” 98 2063
[11] Hothi H S, Makkar A, Sharma J R & Manrao M R 2006 “Eur J Med Chem “41 253
[12] Zhang S, Tu C, and Wang X 2004 “European Journal of Chemistry” 98 4028
[13] Dutta S, Murugkar A, Gandhe N, and Padhye S 2001 “Metal-Based Drugs” 8 183
[14] E. A. Stern,in “x.ray absorption principles and applications, techniques of xafs, sexafs in addition,xanes“edited by (D. C. Koningsberger and Prins. New York. 1988) chi.