Structural and Optical Performance of ZnS Nanoparticles Synthesized via Chemical Route.

G. G. Ramteke¹ , A. S. Lanje² , D. M. Pimpalshende³

1. Department of Physics, Dr. Ambedkar College. Chandrapur-442401, M. S. India.
2. 2Department of Electronics, Dr. Ambedkar College,Chandrapur (M. S.), India.
3. Department of Electronics, Dr. Ambedkar College, Chandrapur-442401, M. S. India.

Correspondence should be addressed to: ggramteke@gmail.com.

Section:Research Paper, Product Type: Isroset-Journal
Vol.6 , Issue.3 , pp.69-74, Jun-2018

CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v6i3.6974

Online published on Jun 30, 2018

Copyright © G. G. Ramteke, A. S. Lanje, D. M. Pimpalshende . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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Abstract :
In this analysis, ZnS nanoparticles have been synthesized employing an easy chemical co-precipitation route using metal precursors and DMF (CH3)2NC(O)H as a stabilizing agent. The obtained ZnS nanoparticles have been characterized through XRD, TEM, UV-Vis, FTIR and PL measurements. The foremost intense broad peaks in the diffraction outline reveal the crystalline character of the prepared material with the particle length is approximately 4.7 nm. The optical band gap has been evaluated from the UV-Vis. absorption spectrum which is found to be about 3.95 eV. The blue swing in absorption spectra validates the formation of nanoparticles. Further, the TEM micrograph revealing the ZnS particles are in nano dimension. FTIR study has been carried out for the bond evaluation. The PL measurement shows the emission of colour in the blue area.

Key-Words / Index Term :
ZnS nanoparticles, XRD, TEM, optical band gap, FTIR, PL

References :
[1] A. S. Lanje, S. J. Sharma, R. S. Ningthoujam, J-S Ahn and R. B. Pode, “Low temperature dielectric studies of zinc oxide (ZnO) nanoparticles prepared by precipitation method”, Advanced Powder. Technology, Vol. 24, pp. 331–335, 2013
[2] S. D. Bompilwar, S. B. Kondawar, V.A. Tabhane, “Impedance study of nanostructure cadmium sulphide and zinc sulphide”, Archives of Applied Science Research, Vol. 2, Issue. 3, pp. 225-230, 2010
[3] R. P. Pawar, “Structural and Optical Properties of Chemically synthesized ZnS Nanoparticles”, Oriental Journal of Chemistry, Vol. 29, Issue. 3, pp. 1139- 1142, 2013
[4] Khalid T. Al-Rasoul, Nada K. Abbas, Zainb J. Shanan, “Structural and optical characterization of Cu and Ni doped ZnS nanoparticles”, International Journal of Electrochemical Science, Vol. 8, pp. 5594-5604, 2013
[5] B. S. Rema Devi, R. Raveendran and A. V. Vaidyan, “Synthesis and Characterization of Mn2 + -doped ZnS Nanoparticles”, Pramana- journal of physics, Vol. 68, Issue. 4, pp. 679-687, 2007
[6] Ravi Sharma, “Studies on thermoluminescence glow curves of Mn doped ZnS nanoparticles”, Recent Research in Science and Technology, Vol. 4, Issue. 8, pp. 34-35, 2012
[7] J. Taghavian and P. Hossein Khanai, “Synthesis and Thermo luminescence properties of ZnS Nanoparticles”, International Journal of Nano Dimensions, Vol. 2, Issue. 2, pp. 125-127, 2011
[8] A. S. Lanje, R. S. Ningthoujam, S. J. Sharma, R. B. Pode, “Luminescence and electrical resistivity properties of cadmium oxide nanoparticles”, Indian Journal of Pure & Applied Physics, Vol. 49, pp. 234-238, 2011
[9] A. S. Lanje, S. J. Sharma, R. B. Pode, R. S. Ningthoujam,“Synthesis and Optical Characterization of Copper oxide Nanoparticles”, Advances in Applied Science Research, Vol. 1, Issue. 2, pp. 36-40, 2010
[10] D. Ayodhya, M. Venkatesham, A. S. Kumari, K. G. Mangatayaru and G. Veerabhadram, “Synthesis, characterization of ZnS nanoparticles by coprecipitation method using various capping agents- photocatalytic activity and kinetic study”, IOSR Journal of Applied Chemistry, Vol. 6, Issue. 1, pp. 01-09, 2013
[11] SHE Yuan-yuan, Yang Juan and QIU Ke-qiang, “Synthesis of ZnS nanoparticles by solid-liquid chemical reaction with ZnO and Na2S underasonic”, Trans. Nanoferrous Metal Society of China,Vol. 20, pp. 211-215, 2010
[12] Baibaswata Bhattacharjee and Chung-Hsin Lu, “Multicolor luminescence of undoped zinc sulphide nanocrystalline thin films at room temperature”, Thin Solid Films, Vol. 514, pp. 132-137, 2006
[13] S. K. Kulkarni, U. Winkler, N. Deshmukh, P. H. Borse, R. Fink and E. Umbach, “Investigation on chemically capped CdS, ZnS, and ZnCdS nanoparticles”, Applied Surface Science, Vol. 169-170, pp. 438-446, 2001
[14] Qihua Xiong, G. Chen, J. d. Acrod, X. Liu et. al., “Optical properties of rectangular cross-sectional ZnS nanowires”, Nano Letters, Vol. 4, Issue. 9, pp. 1663-1668, 2004
[15] Gopa Gosh, Milan Kanti Naskar, Amitava Patra, and Minati Chatterjee, “Synthesis and characterization of PVP- encapsulated ZnS nanoparticles”, Optical Materials, Vol. 28, pp. 1047-1053, 2006
[16] J. P. Borah and K. C. Sharma, “Optical and optoelectronic properties of ZnS nanostructured thin films”, ACTA PHYSICA POLONICA A, Vol. 114, Issue. 4, pp. 713-719, 2008
[17] S. Farjami Shayesteh, S. Kolahi and Y. Azizian-Kalandarragh, “Effect of pH on the structural and optical properties of ZnS nanoparticles embedded in PVA matrix”, Indian Journal of Pure and Applied Physics, Vol. 51, pp. 780-783, 2013
[18] P. K. Mochahari, “Investigation of structural and spectroscopic properties of nanostructured CdS films”, International Journal of Scientific Research In Physics and Applied Sciences, Vol. 5, Issue 6, pp. 1-6, 2017
[19] A. Yakoubi, T. B. Chaabane, A. Aboulaich, R. Mahiou, L. Balan, G. Medjahdi and R. Schneider, “Aqueous synthesis of Cu-doped CdZnS quantum dots with controlled and efficient photoluminescence”, Journal of Luminescence, Vol. 175, pp. 193-202, 2016
[20] C. S. Pathak and M. K. Mandal, “Optical properties of Mn2+ doped ZnS Nanoparticles”, Asian Journal of Chemistry, Vol. 23, Issue. 10, pp. 4655-4658, 2011
[21] U. S. Senapati, D. K. Jha and D. Sarkar, “Green synthesis and characterization of ZnS nanoparticles”, Research Journal of Physical Sciences, Vol. 1, Issue. 7, pp. 1-6, 2013
[22] Ageeth A. Bol, Joke Ferwerda, Jaap A. Bergwerff and Andries Meijerink, “Luminescence of nanocrystalline ZnS:Cu2+”, Journal of Luminescence, Vol. 99, pp. 325-334, 2002
[23] Joseph B. Lambert, et al., “Introduction to Organic Spectroscopy”, Macmillan Publication, New York, pp. 174-177, 1987
[24] Sobia Dilpazir, Mohammad Siddiq and Azhar Iqbal, “Synthesis of Zinc Sulphide Nanostructures by Co-Precipitation: Effect of doping on Electro-optical Properties”, Kenkyu Journal of Nanotechnolgy and Nanoscience., Vol. 1, pp. 34-39, 2015
[25] A. Tiwar, S. J. Dhoble and R. S. Kher, “Influence of thiol capping on the photoluminescence properties of L-cysteine-mercaptoethenol-and mercaptopropionic acid-capped ZnS nanoparticles”, Luminescence, Vol. 30, pp. 1148-1152, 2015
[26] Edgar Mosquera and Nicolas Carvajal, “Low temperature synthesis and blue photoluminescence of ZnS submicronparticles”, Materials Letters, Vol. 129, pp. 8-11, 2014
[27] Akihiko Yoshikawa, Hiroyuki Matsunami and Yasushi Nanishi; “Wide Band gap Semiconductors”, Book, ISBN- 978-3-540-47235-3(online), pp. 1-24, 2007