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Studies of EXAFS Spectra using Copper (II) Schiff Base complexes and Determination of Bond lengths Using Synchrotron Radiation

Mahesh Jamod1 , B.D. Shrivastava2 , Ashutosh Mishra3 , Ashok Kumar Baghel4

Section:Research Paper, Product Type: Isroset-Journal
Vol.6 , Issue.5 , pp.111-114, Oct-2018


CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v6i5.111114


Online published on Oct 31, 2018


Copyright © Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, Ashok Kumar Baghel . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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IEEE Style Citation: Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, Ashok Kumar Baghel, “Studies of EXAFS Spectra using Copper (II) Schiff Base complexes and Determination of Bond lengths Using Synchrotron Radiation,” International Journal of Scientific Research in Physics and Applied Sciences, Vol.6, Issue.5, pp.111-114, 2018.

MLA Style Citation: Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, Ashok Kumar Baghel "Studies of EXAFS Spectra using Copper (II) Schiff Base complexes and Determination of Bond lengths Using Synchrotron Radiation." International Journal of Scientific Research in Physics and Applied Sciences 6.5 (2018): 111-114.

APA Style Citation: Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, Ashok Kumar Baghel, (2018). Studies of EXAFS Spectra using Copper (II) Schiff Base complexes and Determination of Bond lengths Using Synchrotron Radiation. International Journal of Scientific Research in Physics and Applied Sciences, 6(5), 111-114.

BibTex Style Citation:
@article{Jamod_2018,
author = {Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, Ashok Kumar Baghel},
title = {Studies of EXAFS Spectra using Copper (II) Schiff Base complexes and Determination of Bond lengths Using Synchrotron Radiation},
journal = {International Journal of Scientific Research in Physics and Applied Sciences},
issue_date = {10 2018},
volume = {6},
Issue = {5},
month = {10},
year = {2018},
issn = {2347-2693},
pages = {111-114},
url = {https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=904},
doi = {https://doi.org/10.26438/ijcse/v6i5.111114}
publisher = {IJCSE, Indore, INDIA},
}

RIS Style Citation:
TY - JOUR
DO = {https://doi.org/10.26438/ijcse/v6i5.111114}
UR - https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=904
TI - Studies of EXAFS Spectra using Copper (II) Schiff Base complexes and Determination of Bond lengths Using Synchrotron Radiation
T2 - International Journal of Scientific Research in Physics and Applied Sciences
AU - Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, Ashok Kumar Baghel
PY - 2018
DA - 2018/10/31
PB - IJCSE, Indore, INDIA
SP - 111-114
IS - 5
VL - 6
SN - 2347-2693
ER -

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Abstract :
X-ray absorption fine structure (XAFS) at the K-edge of copper has been studied in some copper (II) complexes with substituted anilines like (2Cl, 4Br, 2NO2, 4NO2 and pure aniline) with o-PDA (orthophenylenediamine) as ligand. The X-ray absorption measurements have been performed at the recently developed BL-8 dispersive EXAFS beam line at 2.5 GeV Indus-2 Synchrotron Source at RRCAT, Indore, India. The data obtained has been processed using EXAFS data analysis program Athena. The graphical method gives the useful information about bond length and also the environment of the absorbing atom. The theoretical bond lengths of the complexes were calculated by using interactive fitting of EXAFS using fast Fourier inverse transformation (IFEFFIT) method. This method is also called as Fourier transform method. The Lytle, Sayers and Stern method and Levy’s method have been used for determination of bond lengths experimentally of the studied complexes. The results of both methods have been compared with theoretical IFEFFIT method.

Key-Words / Index Term :
X-ray, K-absorption, XANES copper complexes

References :
[1]. Dhar D N &Taploo C L 1982 J SciInd Res 41.
[2]. Bhattachrya D, Poswal A K, Jha S N, Sangeeta and Sabharwal S C 2009 Bull mater Sci 52.
[3]. Das N C, Jha S N, Bhattacharyya D, Poswal A K, Sinha A K and Mishra V K 2004 Sadhana 29.
[4]. Raman N, Raja Y P and Kulundaisamy A 2009 Proc. Indian Acad. Sci 11.
[5]. Levy R M 1965 J. Chem. Phys. 43.
[6]. Lytle F W 1966 Advances in X-ray Analysis 9.
[7]. Lytle F W, Sayers D E and Stern E A 1975 Phys. Rev. B. 11.
[8]. Stern E A, Sayers D E and Lytle F W 1975 Phys. Rev. B. 11.

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