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X-ray K-absorption studies of XANES copper complexes

Mahesh Jamod1 , B.D. Shrivastava2 , Ashutosh Mishra3

Section:Research Paper, Product Type: Isroset-Journal
Vol.6 , Issue.5 , pp.122-124, Oct-2018


CrossRef-DOI:   https://doi.org/10.26438/ijsrpas/v6i5.122124


Online published on Oct 31, 2018


Copyright © Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 

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IEEE Style Citation: Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, “X-ray K-absorption studies of XANES copper complexes,” International Journal of Scientific Research in Physics and Applied Sciences, Vol.6, Issue.5, pp.122-124, 2018.

MLA Style Citation: Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra "X-ray K-absorption studies of XANES copper complexes." International Journal of Scientific Research in Physics and Applied Sciences 6.5 (2018): 122-124.

APA Style Citation: Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra, (2018). X-ray K-absorption studies of XANES copper complexes. International Journal of Scientific Research in Physics and Applied Sciences, 6(5), 122-124.

BibTex Style Citation:
@article{Jamod_2018,
author = {Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra},
title = {X-ray K-absorption studies of XANES copper complexes},
journal = {International Journal of Scientific Research in Physics and Applied Sciences},
issue_date = {10 2018},
volume = {6},
Issue = {5},
month = {10},
year = {2018},
issn = {2347-2693},
pages = {122-124},
url = {https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=907},
doi = {https://doi.org/10.26438/ijcse/v6i5.122124}
publisher = {IJCSE, Indore, INDIA},
}

RIS Style Citation:
TY - JOUR
DO = {https://doi.org/10.26438/ijcse/v6i5.122124}
UR - https://www.isroset.org/journal/IJSRPAS/full_paper_view.php?paper_id=907
TI - X-ray K-absorption studies of XANES copper complexes
T2 - International Journal of Scientific Research in Physics and Applied Sciences
AU - Mahesh Jamod, B.D. Shrivastava, Ashutosh Mishra
PY - 2018
DA - 2018/10/31
PB - IJCSE, Indore, INDIA
SP - 122-124
IS - 5
VL - 6
SN - 2347-2693
ER -

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Abstract :
The X-ray absorption spectra at the K-edge of copper have been recorded in five mixed ligand copper complexes having orthophenylenediamine as one of the ligand. Various X-ray absorption near edge structure (XANES) parameters, such as chemical shift, i.e., shift of K-edge of copper in complexes with respect to K-edge of copper metal, energy position of principal absorption maximum and edge-width have been determined. Copper has been found to be in oxidation state +2 in all the complexes. From these XANES data the effective nuclear charge on copper and percentage co-valency in these complexes has been estimated.

Key-Words / Index Term :
X-ray, K-absorption, XANES copper complexes

References :
[1]. Srivastav U. C. and Nigam H. L. 1973 Coord. Chem. Rev. 9.
[2]. Nigam A. K and Gupta M. K. 1974 J Phys F 4.
[3]. Sapre V. B. and Mande C. 1972 J. Phys. C 5.
[4]. Clementi E. 1965 IBM J. Res. Dev. Suppl. 9.
[5]. Khan A. H. and Leydeka A. J. 1964 Phys Rev. A 135.

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