Volume-7 , Issue-2 , Jun 2020, ISSN 2348-6341 Go Back

• Open Access   Article

  Spectroscopic Studies on Zinc Barium Oxalate Crystals Grown by Gel Method

  Mangala M. Sanjeevannanavar, Jagannatha N., Rohith P.S.

  Research Paper | Journal-Paper (JPCM)

  Vol.7 , Issue.2 , pp.1-4, Jun-2020

  Abstract

  Full-Text HTML

  References

  Citation

  Abstract
  In the present paper, Zinc mixed Barium Oxalate (ZnBaO) crystals were grown successfully by silica hydrogel technique. The optimum conditions were established by varying various parameters such as specific gravity of Sodium Meta Silicate (SMS), concentration of the oxalic acid (C2H2O4.2H2O) solution, pH of the gel, gel setting time, concentration of reactants like zinc chloride (ZnCl2) and barium chloride (BaCl2.2H2O) etc. Field Emission Scanning Electron Microscope (FESEM) characterization shows the existence of various layers in the grown crystals. Elemental analysis studied by Energy Dispersive X-ray Analysis (EDAX). It determines the percentage composition of elements present in the grown crystals. The study of EDAX confirms the grown crystal has Zn2+, Ba2+, C and O elements. The vibrational analysis of grown crystals identified by FTIR and laser Raman spectroscopy reveals the functional groups like O-H band, C-H band, C=O, C-C bands and metal oxide bands present in the grown crystals. The study of UV-Visible spectrum reveals optical constants like energy bandgap, absorption coefficient, refractive index, reflectance, electrical polarizability and cutoff wavelength of the grown crystal. These constants considered to characterizing materials which are used in various applications like fabrication of optoelectronic devices

  Key-Words / Index Term
  Zinc Barium Oxalate, Silica hydrogel, FESEM, EDAX, FTIR

  References
  [1] M.R.Shedam, Rakesh M.Shed, Shridhar N.Mathad, ? Morphological and FTIR Studies of Barium Oxalate Single Crystals? Acta Chemical IASI. Vol.25, Issue.2, pp.195-207, 2017. l method
  [2] Jagannath, P.Mohan Rao, ?Studies on impurity incorporation in Cadmium oxalate single crystals grown by gel method? Bull Matter Science. Vol.16, Issue.5, pp.365-370, 1993
  [3] P.V.Dalal, K.B.Saraf, ?Growth and study of Barium oxalate Single Crystals in Agar Gel? Bulletin of Material Science. Vol.29, Issue.5, pp.421-425, 2006
  [4] G.Ajithkumar, P.Gupta, J.K.Gin, N.V.Unnikrishnan, ?Juddo-ofelt intensity parameters and laser analysis of PR3+ doped phosphate glasses sensitizeed by Mn2+ ions? Journal of non-cry.solids. Vol.275, pp. 93-106, 2000
  [5] B.Want, M.D.Shah,? Growth and Characterization of terbium Fumarate Heptahydrate Single Crystal? Journal of Crystal growth. Vol.389, pp.39-46, 2014
  [6] S.Alfred Cecil Raj, P. Mariappan, F.Dasiy Selasteen, A. Alagappa Moses? Growth and Study of Calcium Mixed Barium Oxalate Single Crystals in Silica Gel? IJEEE. Vol.1, Issue.7, pp.21-24, 2014
  [7] Muttuselvi.C, Sumathi.B, ?Spectral and Antimicrobial Activity
  Studies on Bis Glycin Hydro Bromide Semi-Organic Crystal?
  The Pharmaceutical and chemical journal. Vol.5, Issue.5, pp.35-45, 2018
  [8] A.MosesEzhil Raj, D.Deva Jayanthi, V.Bena Jothy ?Optimized
  growth and characterization of cadmium oxalate single crystals
  in silica gel? Solid State Science. Vol.10, pp.557-562, 2008.
  [9] P.S. Rohith, N. Jagannatha, ?Growth and Characterization of Pure and Magnesium Doped Copper Cadmium Oxalate Single Crystals?, Materials Today Proceedings, Vol.8, pp.85-93, 2019.
  [10] P.S. Rohith, N. Jagannatha, K V Pradeepkumar, M S Mangala ?Dielectric, Magnetic and Spectral studies of gel grown Mg2+ Doped Copper Cadmium Oxalate Single Crystals?, Journal of Physics: conference series, 1495, 012005,2020.
  [11] N, S. Patil, S. K. Bachchav, D.S.Bhavsar ? Growth and characterization of calcium doped cadmium tartrate crystal by silica gel method? Archives of Applied Science Research. Vol.6, Issue.1, pp.45-51, 2014
  [12] F.D Selasteen, S.A.Cecil Raj, A.Alagappa Moses, F.Emalda Prince, R. Esther Getsy, R. Elakkiya ?Sythensis, Growth and Characterization of Sodium Mixed Cadmium Oxalate Crystals? Journal of Crystallization Process and Technology. Vol.6, pp.11-20, 2016
  [13] K V Pradeep Kumar, N Jagannatha, P S Rohith, ?Effects of light radiation on spectral studies of gel grown Mg2+ doped copper tartrate single crystals? 3rd International Conference on Condensed Matter and Applied Physics (ICC-2019), Bikaner, India, Vol.2220,060008,2020.
  [14] G.Vimal, Kamal P. Mani, Gijo Jose, P.R.Biju, Cyriac Joseph, M.A.Ittyachen ?Growth and Spectroscopic Properties of Sarium Oxalate Single Crystals? Journal of crystal growth. Vol. 404, pp 20-25, 2014
  [15] Mangala M Sanjeevannanavar, N Jagannatha, P.S.Rohith, ?Optical properties of strontium calcium oxalate single crystal grown by gelmmethod? (3rd International Conference on Condensed Matter and Applied Physics (ICC-2019), Bikaner,India, Vol.2220, 060009, 2020.
  [16] N S Patil, P A Savale, S K Bachchav, S T Pawar, ? Synthesis and Characterization of CdTr single Crystals by gel technique? Archives of Physics Research. Vol.2, Issue.1, pp.39-47, 2011
  [17] C.Beekaman, A.A.Reijnders, Y.S.Oh, S.W.Cheong, K.S.Burch ?Raman study of the phonon symmetries in BiFeO3 single crystals? Phys RevB. Vol.86, 020403 (R), 2012
  [18] Yu Ye, J.R.Smyth, S.D.Jacobsen, W.R.Panero, D.A.Brown, T.Katsura, Yun-Yuan Chang, J.P.Townsend, P.Dera, S.Tkachev, C.Unterborn, Z.liu, C.Goujon, ?Crystal structure, Raman and FTIR spectroscopy, and equations of state of OH-bearing MgSiO3 akimotoite? Contrib Mineral Petrol. Vol.166, pp.1375-1388, 2013
  [19] Varghese Mathew, Sabu Jacob, Lizymol Xavier, K.E. Abraham ?Spectroscopic studies of gel-grown lanthanum malonate crystals? Journal of Rare Earths. Vol.30, Issue.3, pp.245- 249, 2012
  [20] A.J.Ali, S.Thangarasu, S. Athimoolam, S.A.Bahadur, ?Factor group, Spectroscopic and Thermal studies on Creatininium hydrogen oxalate monohydrate? Research Journal of Pharmaceutical, Biological and Chemical Sciences. Vol.4, Issue.1, pp.1292-1303, 2013
  [21] K.M.Abedin, M.A.Habib, M. Wahadoszamen, A.I.Talukder, A.F.M. Yusuf Haider, ?Construction of Laser Raman system using diode laser and its performance? Journal of Bangladesh Academy of Sciences, Vol.33, No.1,pp. 55-62, 2009
  [22] C.Muthuselvi, M.Dhavachitra, S.Pandiarajan, ? Growth and Characterization of Aspirin Crystals in the Phosphoric acid medium? Journals of Chemical and Pharmaceutical resaech. Vol.8, Issue 5, pp.804-814, 2016
  [23] R.Selvaraju, S.Sulochana ?Growth, Structural, Morhological and Optical Characterizations of Pure Cadmium doped Calcium Oxalate Monohydrate Crystals? International Journal of Advanced research. Vol.5, Issue.5, pp.1763-1773, 2017
  [24] Jyoti Dalal, Binay Kumar, ?Bulk crystal growth, optical, mechanical and ferroelectric properties of new semiorganic nonlinear optical and piezoelectric Lithium nitrate monohydrate oxalate single crystal? Optical Materials, Vol.51 pp.139?147, 2016
  [25] P.Vasudevan, S.Sankar, D.Jayaraman ?Synthesis, Optical and Electrical Studies of Nonlinear Optical Crystal: L-Arginine Semi-oxilate,? Bull Korean Chem.Soc. Vol.34, Issue.1, pp.128-134, 2013.

  Citation
  Mangala M. Sanjeevannanavar, Jagannatha N., Rohith P.S., "Spectroscopic Studies on Zinc Barium Oxalate Crystals Grown by Gel Method," Journal of Physics and Chemistry of Materials, Vol.7, Issue.2, pp.1-4, 2020