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• Open Access   Article

  Synthesis and Characterization of thermo physical properties of phthalic anhydride glycerol Resin (PAGR) from soybean oil

  S. Abbas, Z. Ahmad

  Research Paper | Journal-Paper (IJSRCS)

  Vol.6 , Issue.5 , pp.1-6, Dec-2019

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  Abstract
  Phthalic anhydride-glycerol Resin(PAGR) increase the flexibility of paint, resist to acid rain effect, increases the adhesiveness, brushing power, film hardness, layer flexibility, durability, gloss retention, resistance to abrasion also helps to decrease the overall drying time of paints. Phthalic anhydride-glycerol Resin is produced by reacting polyfunctional alcohol with the poly basic and monofunctional acid by Alcoholysis process. Moreover, Phthalic anhydride-glycerol Resin(PAGR) is a major raw material for coatings, varnishes and binders. Phthalic anhydride-glycerol Resin(PAGR) is used in paints coating compositions, adhesive, plastics, varnishes, printing ink, floor coverings. In the present research work, Phthalic anhydride-glycerol Resin is synthesized using soybean oil, pentaerythritol, phthalic anhydride and litharge (PbO). It was further characterized by FTIR ,DSC TGA and acid value

  Key-Words / Index Term
  Alcoholysis method, phthalic anhydride glycerol Resin, soybean oil, Pentaerthritol and litharge

  References
  [1] Tapan Kanai, T.K. Mahato, Dhirendra Kumar, Synthesis and characterization of novel silicone acrylate–soya alkydresin as binder for long life exterior coatings, Progress in Organic Coatings 58 (2007) 259–264 .
  [2] Frank et al "Alkyd Resins" in Ullmann`s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.
  [3] E.U. Ikhuoria , M. Maliki , Synthesis and characterisation of chlorinated rubber seed oil alkyd resins, Progress in Organic Coatings 59 (2007) 134–137.
  [4] Waters, R.T. Resins Synthetic, s Alkyd Resins, section 2. London Wyman and son1995.
  [5] Additives for Coatings" J. H. Bielman, Ed. Wiley-VCH, 2000, Weinheim.
  [6] Ikhouria E.U.,Aigbodion, A.I., AND OKIEIMEN F.F Enhancing the quality of Alkyd Resins using Methyl Ester of rubber oil Seed” Triocal Journal of pharmaceutical Research 3. Vol. 3 (1) 2004: 311-317.
  [7] Edwin A. Murillo, Synthesis and characterization of hyper branched alkyd resins based on tall oil fatty acids, Progress in Organic Coatings 69 (2010) 235–240.
  [8] Kirk, encyclopedia of chemical engineering vol.2, 2010.
  [9] Snaler, S.R et al. polymer synthesis and characterization. A laboratory manual USA Academic press . California 1998.
  [10] Pirita Uschanov, Nina Heiskanen Synthesis and characterization of tall oil fatty acids-based alkyd resins and alkyd–acrylate copolymers, Progress in Organic Coatings 63 (2008) 92–99.
  [11] J.S LONG, Filming forming composition, vol 1 New York (1967)72-82.
  [12] Mehlenbancher V.C Official and Testing Methods for the American oil chemists Society Chicago: 35 east Wacker Drive 1950.
  [13] Serdar, Aydin, Hu¨seyin Akc,ay,vThe effects of anhydride type and amount on viscosity and film properties of alkyd resin, Progress in Organic Coatings 51 (2004) 273–279.
  [14] Rebecca Ploeger, Thermal analytical study of the oxidative stability of artists’ alkyd paints Polymer Degradation and Stability Volume 94, (2009)2036-2041.
  [15] G.Guclu, alkyd resin synthesized from PET bottles progress in organic coating 65(2009)362-365.
  

  Citation
  S. Abbas, Z. Ahmad, "Synthesis and Characterization of thermo physical properties of phthalic anhydride glycerol Resin (PAGR) from soybean oil," International Journal of Scientific Research in Chemical Sciences, Vol.6, Issue.5, pp.1-6, 2019

• Open Access   Article

  Removal of Para Chlorophenol (PCP) From Wastewater Using Aluminium/Graphite Electrode by Electrochemical Method

  S. Abbas, Z. Ahmad, Q.B. Akbar

  Research Paper | Journal-Paper (IJSRCS)

  Vol.6 , Issue.5 , pp.7-12, Dec-2019

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  Abstract
  An experimental study was conducted to evaluate the feasibility and application of aluminum/ Graphite Electrode in electrochemical method for the removal of Parachlorophenol from Wastewater under local conditions. Removal of PCP is important issue in the world, as PCP is carcinogenic, skin sensitive, bones and lungs damage compound. A sample was prepared in laboratory, obtained 1500 ml of 200ppm p-Cholorophenol and treated in reactor in which Aluminium electrodes & Graphite Electrode installed. Added 0. 5 gm NaCl into remedy as reaction enhancer. Factors affecting on the removal of Para Chlorophenol was investigated are; varying electric voltage (10 Volts,20 volts), varying treatment time (20 Min, 60 Min) and different electrodes (Aluminium, Graphite). After treatment sample was tested by Gas Chromatography which given PCP values (0.998-0.999). it was investigated from results that removal efficiency of Para Chloro phenol increased with increasing voltage supply (20 Volts), reaction time (60 Min) and Aluminium Electrode. According to these results, the effect of Treatment time on the removal of Parachlorophenol is more than Voltage and Aluminium Electrode. Aluminium electrode efficiency is high than Graphite. When we compare Time & voltage, time & different electrodes, then removal efficiency is maximum at higher time, higher voltage and by using Aluminium electrode.

  Key-Words / Index Term
  Electrochemical, Para Chlorophenol, Wastewater, Aluminium Electrode

  References
  [1] E. Dıaz, A.F. Mohedano, L. Calvo,M.A. Gilarranz, J.A. Casas, J.J. Rodrıguez, Hydrogenation of phenol in aqueous phase with palladium on activated carbon catalysts, Chem. Eng. J. 131 (2007) 65–71.
  [2] L. John Kennedy, J. Judith Vijaya, K. Kayalvizhi, G. Sekaran, Adsorption of phenol from aqueous solutions using mesoporous carbon prepared by two-stage process, Chem. Eng. J. 132 (2007) 279–287.
  [3] J. Huang, X. Wang, Q. Jin, Y. Liu, Y. Wang, Removal of phenol from aqueous solution by adsorption onto OTMAC-modified attapulgite, J. Environ. Manage. 84 (2007) 229–236.
  [4] O. Tepe, A.Y. Dursun, Combined effects of external mass transfer and biodegradation rates on removal of phenol by immobilized Ralstonia eutropha in a packed bed reactor, J. Hazard. Mater. 151 (2008) 9–16.
  [5] M.S.A. Palma, J.L. Paiva, M. Zilli, A. Converti, Batch phenol removal frommethyl isobutyl ketone by liquid–liquid extraction with chemical reaction, Chem. Eng. Process. 46 (2007) 764–768.
  [6] W.H. Hallenbeck, K.M. Cunningham, Quantitative Risk Assessment for Environmental and Occupational Health, Burns Lewis Publishers, 1986.
  [7] G. Annadurai, R. Juang, D.J. Lee, Microbial degradation of phenol using mixed liquors of Pseudomonas putida and activated sludge,Waste Manage. 22 (2002) 703–710.
  [8] D. Mohan, S. Chander, Single component and multi-component adsorption of phenols by activated carbons, Colloids Surf. A: Physicochem. Eng. Aspects 177 (2001) 183–196.
  [9] G. Dursun, H. C， ic，ek, A.Y. Dursun, Adsorption of phenol from aqueous solution by using carbonised beet pulp, J. Hazard. Mater. B125 (2005) 175–182.
  [10] A. Gurses, M. Yalcin, Removal of phenolic and lignin compounds from bleached kraft mill effluent by fly ash and sepiolite, Adsorption 11 (2005) 87–97.
  [11] Y. Yavuz, A.S. Koparal, Electrochemical oxidation of phenol in a parallel plate reactor using ruthenium mixed metal oxide electrode, J. Hazard. Mater. B136 (2006) 296–302.
  [12] P. Canizares, F. Martinez, J. Garcia-Gomez, C. Saez, M.A. Rodrigo, Combined electrooxidation and assisted electrochemical coagulation of aqueous phenol wastes, J. Appl. Electrochem. 32 (2002) 1241–1246.
  [13] K. Nazari, N. Esmaeili, A. Mahmoudi, H. Rahimi, A.A. Moosavi-Movahedi, Peroxidative phenol removal from aqueous solutions using activated peroxidise biocatalyst, Enzyme Microb. Technol. 41 (2007) 226–233.
  [14] H. Kuramitz, Y. Nakata, M. Kawasaki, S. Tanaka, Electrochemical oxidation of bisphenol A. Application to the removal of bisphenol A using a carbon fiber electrode, Chemosphere 45 (2001) 37–43.
  [15] K. Rajeshwar, J.G. Ibanez, G.M. Swain, Electrochemistry and the environment, J. Appl. Electrochem. (1994) 24.
  [16] L. Szpyrkowicz, J. Naumczyk, F. Zilio-Grandi, Electrochemical treatment of Tannery wastewater using Ti/Pt/Ir electrodes, Water Res. 29
  (1995) 517–524.
  [17] K. Vijayaraghavan, T.K. Ramanujam, N. Balasubramanian, In situ hypochlorous acid generation for treatment of tannery wastewaters, J. Environ. Eng. 124 (1998) 887–891.
  [18] L. Szpyrkowicz, C. Juzzolino, S.N. Kaul, S. Daniele, M.D.De. Faveri, Electrochemical oxidation of dyeing baths bearing disperse Health A33 (1998) 847–862. Dyes, Ind. Eng. Chem. Res. 39 (2000) 3241–3248.
  [20] A.G. Vlyssides, C.J. Israilides, Electrochemical oxidation of a textile dye and finishing wastewater using a Pt/Ti electrode, J. Environ. Sci.
  [21] J.O’M. Bockris (Ed.), Electrochemistry of Cleaner Environments, Plenum, New York, 1972.
  [22] D. Pletcher, F. Walsh (Eds.), Industrial Electrochemistry, Chapman and Hall, London, 1990.
  [23] D. Pletcher, N.L. Weinberg, Chem. Eng. (London) (1992) Aug. 98–103, Nov. 132–141.
  [24] K. Rajeshwar, J.G. Ibanez, G.M. Swain, J. Appl. Electrochem. 24 (1994) 1077.
  [25] K. Rajeshwar, J.G. Ibanez, Fundamentals and Application in Pollution Abatement, Academic Press, San Diego, CA, 1997.
  [26] C.A.C. Sequeira (Ed.), Environmentally Oriented Electrochemistry, Elsevier, Amsterdam 1994.
  [27] P. Tatapudi, J.M. Fenton, in: H. Gerischer, C.W. Tobias (Eds.), Advances in Electrochemical Science and Engineering, vol. 4, VCH Verlagsgesellschaft, Weinheim, 1995, p. 363.
  [28] D. Simonson, Chem. Soc. Rev. 26 (1997) 181.
  [29] M. Carmona, M. Khemis, J. Leclerc, F. Lapicque, A simple model to predict the removal of oil suspensions from water using the electrocoagulation technique, Chem. Eng. Sci. 61 (2006) 1237–1246.
  [30] A.E. Yilmaz, R. Boncukcuoglu, M.M. Kocakerim, B. Keskinler, The investigation of parameters affecting boron removal by electrocoagulationmethod, J. Hazard. Mater. B125 (2005) 160–165.
  [31] M. Kobya, E. Demirbas, O.T. Can, M. Bayramoglu, Treatment of levafix orange textile dye solution by electrocoagulation, J. Hazard. Mater. B132 (2006) 183–188.
  [32] M. Bayramoglu, O.T. Can, M. Kobya, M. Sozbir, Operating cost analysis of electrocoagulation of textile dye wastewater, Sep. Purif. Technol. 37 (2004) 117–125.
  

  Citation
  S. Abbas, Z. Ahmad, Q.B. Akbar, "Removal of Para Chlorophenol (PCP) From Wastewater Using Aluminium/Graphite Electrode by Electrochemical Method," International Journal of Scientific Research in Chemical Sciences, Vol.6, Issue.5, pp.7-12, 2019

• Open Access   Article

  Composite Catalytic System for the Conversion of Carbon Dioxide to Useful Compound

  S. Abbas, Z. Ahmad

  Research Paper | Journal-Paper (IJSRCS)

  Vol.6 , Issue.5 , pp.13-18, Dec-2019

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  Abstract
  This experimental work done on the production of valuable product from Carbon dioxide by composite catalytic conversion system of carbon dioxide to Alcoholic and acidic compounds. Different mixtures of catalysts utilized to check and enhanced the reactivity of the system as well as increased the production of Valuable product from Carbon dioxide: Fischer-Tropsch synthesis, hydrogenation, water-gas-shift and methanol synthesis. These results showed that composite catalytic system played important role for the syntheses of valuable products from Carbon Dioxide. We have concluded that if methanol synthesis sites were present adjacent to the carbon –carbon chain growth sites, the formation rate of C2 oxygenates would be increases. Production of methanol increased by increasing temperature and using of catalyst PdZnAl in composite catalytic system. Composite catalyst (PdZnAl ) was stable at high temperature 390 ◦C. It was showed that conversion efficiency was high at high temperature. The results showed that the process can be emphasize by operating at high temperature using Pd-based methanol synthesis catalyst. Organic Byproduct of the steam reforming was demonstrated that a means to facilitate additional hydrogen. Primary process design for the Composite Catalytic System for The Conversion of Carbon Dioxide to Valuable Compound, simulation, and economic analysis of the proposed were carried out. It is observed from analyses data Cost of the Carbon dioxide and hydrogen increase the production cost of the Methanol

  Key-Words / Index Term
  CO2 utilization; syngas. higher alcohols; Fischer-Tropsch

  References
  [1] Erdogan,alper, oze yuksel, orhan, amanuscript accepted, co2 utilization: development in conversation process, 2016.
  [2] cooper h w. chem eng prog, 2010, 106(2): 24
  [3] centi g, cum g, fierro j l g, lopez nieto j m. direct con-version of methane, ethane and carbon dioxide to fuels and chemicals, 2008, cap report, the catalyst group resources
  [4] Ritter S K. Chem Eng News, 2007, 85(18): 11
  [5] Graham-Rowe D. New Sci, 2008, 197(2645): 32
  [6] Inui T, Yamamoto T, Inoue M, Hara H, Takeguchi T, Kim J B. Appl Catal A, 1999, 186(1-2): 395
  [7] Lebarbier V M, Dagle R A, Kovarik L, Lizarazo-Adarme J A,
  [8] Centi G, Perathoner S. Catal Today, 2009, 148(3-4): 191
  [9] Inui T, Hara H, Takeguchi T, Kim J B. Catal Today, 1997, 36(1): 25
  [10] Inui T, Yamamoto T. Catal Today, 1998, 45(1-4): 209
  [11] Subramanian N D, Gao J, Mo X H, Goodwin J G, Torres W, Spivery J J. J Catal, 2010, 272(2): 204
  [12] Gerber M A, White J F, Gray M J, Thompson B L, Stevens D J. Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis-2009 Progress Report, December 2010, PNNL-DOE Formal Report
  [13] Christensen J M, Mortensen P M, Trane R, Jensen P A, Jensen A D. Appl Catal A, 2009, 366(1): 29
  [14] King D L, Palo D R. Catal Sci Technol, 2012, 2(10): 2116.
  [15]Xia G, Holladay J D, Dagle R A, Jones E O, Wang Y. Chem Eng Technol, 2005, 28(4): 515
  [16]Twigg M V ed. Catalyst Handbook, 2nd ed. London: Wolfe Publishing Ltd., 1989
  [17]Hu J L, Dagle R A, Holladay J D, Cao C S, Wang Y, White F, Elliott D C, Stevens D J. US Patent 7858667, 2007
  [18]Chin Y H, Dagle R, Hu J L, Dohnalkova A C, Wang Y. Catal Today, 2002, 77(1-2): 79
  [19]Hu J L, Wang Y, Cao C S, Elliott D C, Stevens D J, White J F. Catal Today, 2007, 120(1): 90
  [20] Soudabeh Rahmani,a Fereshteh Meshkani ,a,b and Mehran Rezaeia,b, Preparation of Ni-M (M: La, Co, Ce, and Fe) Catalysts Supported on Mesoporous Nano crystalline γ-Al2O3 for CO2 Methanation, published online 00 Month 2018 in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/ep.13040.
  [21] Rashi Gusain, Pawan Kumar, Om P.Sharma, Suman L.Jain,OmP.Khatri,Reduced graphene oxide-CuO nano composites for photo catalytic conversion of CO2 into methanol under visible light irradiation, Applied Catalysis B, Environmental http://dx.doi.org/10.1016/j.apcatb.2015.08.012.
  

  Citation
  S. Abbas, Z. Ahmad, "Composite Catalytic System for the Conversion of Carbon Dioxide to Useful Compound," International Journal of Scientific Research in Chemical Sciences, Vol.6, Issue.5, pp.13-18, 2019

• Open Access   Article

  Conjugation of Organic Dyes Onto pH Insensitive Silver Nanoparticles for pH Sensing

  J.A. Owusu, K.E. Pobee-Quaynor

  Research Paper | Journal-Paper (IJSRCS)

  Vol.6 , Issue.5 , pp.19-25, Dec-2019

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  Abstract
  pH is a very important parameter in research, production and quality assessment in the fields of life sciences, pharmaceuticals and food industries. Over the years, several methods have been employed to enhance the sensing of pH. This article, however, concentrates on using fluorescence-based nanosensor detection due to its high spatial resolution, fast response, high sensitivity, simple usage and versatility to other detection schemes. Herein, a 2nm size G-AgNPs were synthesized and conjugated to a well-known pH-sensitive dye (NHS-FAM) and a pH insensitive dye (NHS-TAMRA) to produce a fluorescent pH nanoprobe sensor. After conjugating NHS-FAM to G-AgNPs, it showed an increment in fluorescent intensity over a wide range of pH values which led to an R2 value of 0.9992. NHS-TAMRA conjugated onto the as-prepared AgNPs also showed increment in fluorescent intensity over pH values of 5-10 which resulted in linear regression (R2) value of 0.9866

  Key-Words / Index Term
  pH, Silver nanoparticles, NHS – 5(6) – carboxytetramethylrhodamine N-succinimidyl ester, 5(6) – carboxytetramethylrhodamine N-succinimidyl ester, Fluorescence, Nanoprobe

  References
  [1] B. O. Noqtah, "pH effect on the aggregation of silver nanoparticles synthesized by chemical reduction," Versita, vol. 32, no. 1, pp. 107–111, 2014.
  [2] O. V Salata, "Applications of nanoparticles in biology and medicine," J. Nanobiotechnology, vol. 6, pp. 1–6, 2004.
  [3] V. V Mody, R. Siwale, A. Singh, and H. R. Mody, "Introduction to metallic nanoparticles," Pharm. bioallied Sci., vol. 2, no. 4, 2010.
  [4] J. Dobson, "Gene therapy progress and prospects: Magnetic nanoparticle-based gene delivery," Gene Ther., vol. 13, no. 4, pp. 283–287, 2006.
  [5] S. Rudge, C. Peterson, C. Vesely, J. Koda, S. Stevens, and L. Catterall, "Adsorption and desorption of chemotherapeutic drugs from a magnetically targeted carrier (MTC)," J. Control. Release, vol. 74, no. 1–3, pp. 335–340, 2001.
  [6] J. Natsuki, T. Natsuki, and Y. Hashimoto, "A Review of Silver Nanoparticles : Synthesis Methods, Properties, and Applications," Int. J. Mater. Sci. Appl., vol. 4, no. 5, pp. 325–332, 2015.
  [7] A. Syafiuddin, Salmiati, M. R. Salim, A. H. Kueh, T. Hadibarata, and H. Nur, "A Review of Silver Nanoparticles: Research Trends, Global Consumption, Synthesis, Properties, and Future Challenges," J. Chin. Chem. Soc, vol. 64, pp. 732–756, 2017.
  [8] Q. H. Tran, V. Q. Nguyen, and A. Le, "Silver nanoparticles : synthesis, properties, toxicology, applications and perspectives," Adv. Nat. Sci., vol. 4, p. 20, 2013.
  [9] K. Lee and M. A. El-Sayed, "Gold and Silver Nanoparticles in Sensing and Imaging : Sensitivity of Plasmon Response to Size, Shape, and Metal Composition," J. Phys. Chem, vol. 110, pp. 19220–19225, 2006.
  [10] L. R. Hirsch et al., "Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance," P. Natl. Acad. Sci., vol. 100, no. 23, pp. 13549–13554, 2003.
  [11] D. A. Stuart, A. J. Haes, C. R. Yonzon, E. M. Hicks, and R. P. Van Duyne, "Biological applications of localized surface plasmonic phenomena," Nanobiotecnol., vol. 152, no. 1, pp. 13–32, 2005.
  [12] X. Zhang, Z. Liu, W. Shen, and S. Gurunathan, "Silver Nanoparticles : Synthesis, Characterization, Properties, Applications, and Therapeutic Approaches," Int. J. Mol. Sci., vol. 17, p. 1534, 2016.
  [13] C. Caro, P. M., R. Klippstein, D. Pozo, and A. P., "Silver Nanoparticles: Sensing and Imaging Applications," Silver Nanoparticles, pp. 201–224, 2010.
  [14] H. D. Beyene, A. A. Werkneh, H. K. Bezabh, and T. G. Ambaye, "Synthesis paradigm and applications of silver nanoparticles (AgNPs)," Sustain. Mater. Technol., 2017.
  [15] J. Han and K. Burgess, "Fluorescent Indicators for Intracellular pH - Chemical Reviews," Chem. Rev., vol. 110, no. 5, pp. 2709–2728, 2010.
  [16] H. R. Kermis, Y. Kostov, G. Rao, and B. Engineering, "Analyst Sensor," RSC Anal., vol. 128, pp. 1181–1186, 2003.
  [17] A. Iovescu et al., "Ageing of fluorescent and smart naphthalene labeled poly(acrylic acid)/cationic surfactant complex," Colloids Surfaces A Physicochem. Eng. Asp., 2017.
  [18] P. K. Ang, W. Chen, A. Thye, S. Wee, and K. P. Loh, "Solution-Gated Epitaxial Graphene as pH Sensor," Am. Chem. Soc., vol. 130, pp. 14392–14393, 2008.
  [19] Z. Yang et al., "Fluorescent pH sensor constructed from a heteroatom-containing luminogen with tunable AIE and ICT characteristics," RSC Chem. Sci., 2013.
  [20] Y. Lu and B. Yan, "A ratiometric fluorescent pH sensor based on nanoscale metal-organic frameworks (MOFs) modified by europium(III) complexes," ChemComm., vol. 253, pp. 13323–13326, 2014.
  [21] L. Ferrari, L. Rovati, P. Fabbri, and F. Pilati, "Disposable Fluorescence Optical pH Sensor for Near Neutral Solutions," Sensors, vol. 13, pp. 484–499, 2013.
  [22] H. Ramsay, D. Simon, E. Steele, A. Hebert, R. D. Oleschuk, and K. G. Stamplecoskie, "The power of fluorescence excitation-emission matrix (EEM) spectroscopy in the identification and characterization of complex mixtures of fluorescent silver clusters," RSC Adv., vol. 8, no. 73, pp. 42080–42086, 2018.
  [23] S. Kalele, A. C. Deshpande, S. B. Singh, and S. K. Kulkarni, "Tuning luminescence intensity of RHO6G dye using silver nanoparticles," Bull. Mater. Sci., vol. 31, no. 3, pp. 541–544, 2008.
  [24] J. Zhang and J. R. Lakowicz, "Enhanced Luminescence of Phenyl-phenanthridine Dye on Aggregated Small Silver Nanoparticles," J. Phys. Chem, vol. 109, pp. 8701–8706, 2005.
  [25] S. Sun, X. Ning, G. Zhang, Y. Wang, C. Peng, and J. Zheng, "Dimerization of Organic Dyes on Luminescent Gold Nanoparticles for Ratiometric pH Sensing Zuschriften Angewandte," Angew. Chemie - Int. Ed., vol. 128, pp. 2467–2470, 2016.
  

  Citation
  J.A. Owusu, K.E. Pobee-Quaynor, "Conjugation of Organic Dyes Onto pH Insensitive Silver Nanoparticles for pH Sensing," International Journal of Scientific Research in Chemical Sciences, Vol.6, Issue.5, pp.19-25, 2019

• Open Access   Article

  Luminescent Gold Nanoparticles for Temperature Sensing

  J.A. Owusu, K.E. Pobee-Quaynor

  Review Paper | Journal-Paper (IJSRCS)

  Vol.6 , Issue.5 , pp.26-32, Dec-2019

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  Abstract
  Temperature is a critical parameter that influences activities of living organisms at various levels and also governs biochemical reactions in molecules as it defines their state and dynamics. Several methods have been applied for the sensing of temperature, but this work concentrates on using fluorescence-based nano-sensors detection methods due to their fast response, high spatial resolution, high-temperature resolution, and safety of remote handling. In this review, the emphasis is made on gold nanoparticles utilized as nanothermometers for both local and intracellular thermometry due to its good biocompatibility, high stability, and low cytotoxicity. Furthermore, these fluorescence temperature-dependent AuNPs were used as nanoprobes to measure temperatures at a different range. Moreover, this process is reversible, which illustrates that the fluorescence intensity of AuNPs can be regained to the initial intensity

  Key-Words / Index Term
  Temperature, Fluorescence, Gold nanoparticles, Gold nanoclusters, Nanothermometer

  References
  [1] S. Uchiyama, C. Gota, T. Tsuji, and N. Inada, "Intracellular temperature measurements with fluorescent polymeric thermometers," Chem. Commun., vol. 53, no. 80, pp. 10976–10992, 2017.
  [2] C. Wang, L. Ling, Y. Yao, and Q. Song, "One-step synthesis of fluorescent smart thermo-responsive copper clusters: A potential nanothermometer in living cells," Nano Res., vol. 8, no. 6, pp. 1975–1986, 2015.
  [3] C. Wang, Z. Xu, H. Cheng, H. Lin, M. G. Humphrey, and C. Zhang, "A hydrothermal route to water-stable luminescent carbon dots as nanosensors for pH and temperature," Carbon N. Y., vol. 82, no. C, pp. 87–95, 2015.
  [4] O. Kohki, S. Reiko, S. Beini, and K. Shigeki, "Intracellular thermometry with fluorescent sensors for thermal biology," 2018.
  [5] H. Zhao, A. Vomiero, and F. Rosei, "Ultrasensitive, Biocompatible, Self-Calibrating, Multiparametric Temperature Sensors," Small, vol. 11, no. 43, pp. 5741–5746, 2015.
  [6] C. Gota, K. Okabe, T. Funatsu, Y. Harada, and S. Uchiyama, "Hydrophilic fluorescent nanogel thermometer for intracellular thermometry," J. Am. Chem. Soc., vol. 131, no. 8, pp. 2766–2767, 2009.
  [7] J. Qiao et al., "Thermal responsive fluorescent block copolymer for intracellular temperature sensing," J. Mater. Chem., vol. 22, no. 23, pp. 11543–11549, 2012.
  [8] F. Ye, C. Wu, Y. Jin, Y. Chan, X. Zhang, and D. T. Chiu, "Ratiometric Temperature Sensing with Semiconducting Polymer Dots," pp. 8146–8149, 2011.
  [9] G. Kucsko et al., "Nanometre-scale thermometry in a living cell," pp. 4–9.
  [10] B. Seiichi Uchiyama,*a Toshikazu Tsuji,*a, b Kumiko Ikado, b Aruto Yoshida and a T. H. and N. I. Kyoko Kawamoto, "A cationic fluorescent polymeric thermometer for the ratiometric sensing of intracellular temperature," 2015.
  [11] D. Jaque, E. Martín, L. Martínez, and P. Haro-, "Fluorescent nanothermometers for intracellular thermal sensing," vol. 9, pp. 1047–1062, 2014.
  [12] A. E. Albers, E. M. Chan, P. M. Mcbride, C. M. Ajo-franklin, B. E. Cohen, and B. A. Helms, "Dual-Emitting Quantum Dot/Quantum Rod-Based Nanothermometers with Enhanced Response and Sensitivity in Live Cells," pp. 3–6, 2012.
  [13] Z. Jingyue and F. Bernd, "Synthesis of gold nanoparticles via chemical reduction methods," nanocon, 2015.
  [14] A. Carattino, M. Caldarola, and M. Orrit, "Gold Nanoparticles as Absolute Nanothermometers." pp. 874–880, 2018.
  [15] L. Tong, Q. Wei, A. Wei, and J. Cheng, "Review Gold Nanorods as Contrast Agents for Biological Imaging : Optical Properties, Surface Conjugation, and Photothermal Effects †," pp. 21–32, 2009.
  [16] J. Zheng, C. Zhou, M. Yu, and J. Liu, "Nanoscale Different sized luminescent gold nanoparticles," 2012.
  [17] Y. Yeh, B. Creran, and V. M. Rotello, "Nanoscale Gold nanoparticles : preparation, properties, and applications in," pp. 1871–1880, 2012.
  [18] X. Huang, I. H. El-Sayed, W. Qian, and M. A. El-Sayed, "Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods," no. 3, pp. 2115–2120, 2006.
  [19] X. Huang, P. K. Jain, and I. H. El-Sayed, "Plasmonic photothermal therapy ( PPTT ) using gold nanoparticles," pp. 217–228, 2008.
  [20] T. Zhao et al., "Gold Nanorod Enhanced Two-Photon Excitation Fluorescence of Photosensitizers for Two-Photon Imaging and Photodynamic Therapy," 2014.
  [21] H. Weng, T. B. Huff, and P. S. Low, "In vitro and in vivo two-photon luminescence imaging of single gold nanorods," 2005.
  [22] Y. Matsuda, T. Torimoto, T. Kameya, T. Kameyama, and S. Kuwabata, "Sensors and Actuators B : Chemical ZnS – AgInS 2 nanoparticles as a temperature sensor," vol. 176, pp. 505–508, 2013.
  [23] W. Zhang et al., "of luminescent gold nanocluster-embedded peptide nanofibers for temperature sensing and cellular imaging Supramolecular self-assembly bioinspired synthesis of luminescent gold nanocluster-embedded peptide nanofibers for temperature sensing and cellular," 2017.
  [24] M. B. Mohamed, V. Volkov, S. Link, and M. A. El-Sayed, "0787.Chem.Phys.Lett.2000,317,517.pdf," no. February, pp. 517–523, 2000.
  [25] F. Toderas, M. Iosin, and S. Astilean, "Luminescence properties of gold nanorods," Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. with Mater. Atoms, vol. 267, no. 2, pp. 400–402, 2009.
  [26] B. Nikoobakht and M. A. El-Sayed, "Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method," no. 16, pp. 1957–1962, 2003.
  [27] J. Li, M. Gu, and S. Member, "Gold-Nanoparticle-Enhanced Cancer Photothermal Therapy," vol. 16, no. 4, pp. 989–996, 2010.
  [28] A. Martín-Barreiro, S. De Marcos, and J. Galbán, "Gold nanoclusters as a quenchable fluorescent probe for sensing oxygen at high temperatures," vol. 2, pp. 1–7, 2018.
  [29] Y. T. Wu, C. Shanmugam, W. Bin Tseng, M. M. Hiseh, and W. L. Tseng, "A gold nanocluster-based fluorescent probe for simultaneous pH and temperature sensing and its application to cellular imaging and logic gates," Nanoscale, vol. 8, no. 21, pp. 11210–11216, 2016.
  [30] Y. Sun, J. Wu, C. Wang, Y. Zhaoa, and Q. Lin, "Tunable Near-Infrared Fluorescent Gold Nanoclusters: Temperature Sensor and Targeted Bioimaging," NJC, 2017.
  [31] J. Bomm, C. Günter, and J. Stumpe, "Synthesis and optical characterization of thermosensitive, luminescent gold nanodots," J. Phys. Chem. C, vol. 116, no. 1, pp. 81–85, 2012.
  [32] Z. Wang, X. Ma, S. Zong, Y. Wang, H. Chen, and Y. Cui, "Preparation of a magnetofluorescent nano-thermometer and its targeted temperature sensing applications in living cells," Talanta, vol. 131, pp. 259–265, 2015.
  [33] A. Bar-Cohen, P. Wang, and E. Rahim, "Thermal management of high heat flux nanoelectronic chips," Microgravity Sci. Technol., vol. 19, no. 3–4, pp. 48–52, 2007.
  [34] M. A. Van Dijk et al., "Absorption and scattering microscopy of single metal nanoparticles," Phys. Chem. Chem. Phys., vol. 8, no. 30, pp. 3486–3495, 2006.
  [35] X. H. Vu, M. Levy, T. Barroca, H. N. Tran, and E. Fort, "Gold nanocrescents for remotely measuring and controlling local temperature," Nanotechnology, vol. 24, no. 32, 2013.
  [36] K. Okabe, N. Inada, C. Gota, Y. Harada, T. Funatsu, and S. Uchiyama, "Intracellular temperature mapping with a fluorescent polymeric thermometer and fluorescence lifetime imaging microscopy," Nat. Commun., vol. 3, pp. 705–709, 2012.
  [37] H. M. Pollock and A. Hammiche, "Micro-thermal analysis: Techniques and applications," J. Phys. D. Appl. Phys., vol. 34, no. 9, pp. 23–53, 2001.
  [38] G. Baffou, M. P. Kreuzer, F. Kulzer, and R. Quidant, "Temperature mapping near plasmonic nanostructures using fluorescence polarization anisotropy," Opt. Express, vol. 17, no. 5, p. 3291, 2009.
  [39] X. Chen, J. B. Essner, and G. A. Baker, "Exploring luminescence-based temperature sensing using protein-passivated gold nanoclusters," Nanoscale, vol. 6, no. 16, pp. 9594–9598, 2014.
  [40] L. Shang, F. Stockmar, N. Azadfar, and G. U. Nienhaus, "Angewandte Intracellular Thermometry by Using Fluorescent Gold Nanoclusters **," pp. 11154–11157, 2013.
  [41] M. Nakano and T. Nagai, "Thermometers for monitoring cellular temperature," J. Photochem. Photobiol. C Photochem. Rev., vol. 30, pp. 2–9, 2017.
  [42] M. Y. Berezin and S. Achilefu, "Fluorescence lifetime measurements and biological imaging," Chem. Rev., vol. 110, no. 5, pp. 2641–2684, 2010.
  [43] P. Marco and A. Kenneth, "Biomolecular Coronas Provide the Biological Identity of Nanomaterials," pp. 0–26, 2012.
  

  Citation
  J.A. Owusu, K.E. Pobee-Quaynor, "Luminescent Gold Nanoparticles for Temperature Sensing," International Journal of Scientific Research in Chemical Sciences, Vol.6, Issue.5, pp.26-32, 2019