Volume-9 , Issue-4 , Dec 2022, ISSN 2348-635X Go Back
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Open Access Article
N. Gandhi, Sree laxmi, D. Madhusudhan Reddy, Ch. Vijaya
Research Paper | Journal-Paper (WAJES)
Vol.9 , Issue.4 , pp.1-15, Dec-2022
Abstract
The current study describes a green method for synthesis of silica nanoparticles (SiNPs) from banana peels (Musa paradisiaca). Utilizing the Ultraviolet-Visible (UV-Vis) Spectrophotometer, Fourier Transform Infrared (FT-IR), Dynamic Light Scattering (DLS) and Zeta, X-ray Diffractometer (XRD), Scanning Electron Microscope (SEM), and Energy Dispersion Spectroscopy (EDS), these SiNPs were characterized and their effectiveness at inhibiting the growth of various microorganisms was when these SiNPs were synthesised, they displayed a colour change pattern, and a UV-Visible spectrophotometer analysis revealed a broad peak at 365 nm. The presence of Si content, as well as the appearance of phytochemicals such primary amines of proteins and significant amounts of fibre, were revealed by FT-IR analysis to be the essential factors in the capping and stabilisation of SiNPs. Nanoparticles had an average size of 45 nm and a zeta potential value of 21.3 mV, according to DLS and zeta potential measurements. An XRD analysis revealed a broad peak at 22o and 26o of 2? value, confirming the amorphous nature of the nanoparticles and their average size range of 35 nm. The particles were poly-dispersed, spherical in shape, and ranged in size from 7 to 60 nm with negligible agglomeration among the particles, according to higher magnification examinations with SEM analysis. A 45.22 weight percentage of silica was found in the sample by energy dispersive X-ray analysis, which points to the sample`s extreme purity. Gram positive and gram negative bacteria are used to test the produced nanoparticles for growth inhibitory action on various microorganisms, potentially showing inhibitory activity. The fruit peel of Musa paradisiaca was shown to be an effective and dependable green source for the manufacture of possible bio antibacterial SiNPs, according to the study`s findings. The current study also offers an accurate explanation of the physiochemical and biological approach of silica nanoparticles in plants, which promotes safer and more environmentally friendly agriculture and better plant growth.Key-Words / Index Term
Musa paradisiaca fruit peel (Banana), silica nanoparticles, microwave, FTIR, XRD, SEM, EDX, Uv-visible spectrophotometer, antimicrobial activity and physiological, biochemical analysis.References
[1]. N. Gandhi, D. Sirisha and Vikas Chandra Sharma.”Microwave-Mediated Green Synthesis of Silver Nanoparticles Using Ficus elastica Leaf Extract and Application in Air pollution Controlling Studies”. International Journal of Engineering Research and Applications. Vol. 4, issue 1, pp. 01-12, 2014.
[2]. N. Gandhi, D. Sirisha, M. Hasheena and Smita Asthana. “Eco-friendly Method for Synthesis of Copper Nanoparticles and Application for removal of Aqueous Sulphur Dioxide (SO2) and Nitrogen Dioxide (NO2)”. International Journal of Engineering Research and Technology. Vol. 3, issue 11, pp.1253-1262, 2014.
[3]. N. Gandhi, Y. Shruthi, G. Sirisha and C.R. Anusha. “Facile and Eco-Friendly Method for Synthesis of Calcium Oxide (CaO) Nanoparticles and its Potential Application in Agriculture”. The Saudi Journal of Life Sciences. Vol. 6, issue 5, pp. 89-103, 2021.
[4]. N. Gandhi, D. Sirisha, Smita Asthana. “Phytoremediation of Lead (Pb) Contaminated Soil by Using Sorghum bicolor”. Research & Reviews in Bio Sciences. Vol.10, issue 9, pp. 333 – 342, 2015.
[5]. F. Adam, T.S. Chew, J. Andas. “A simple template-free sol–gel synthesis of spherical nanosilica from agricultural biomass”. J Sol–Gel Sci Technol. Vol. 59, pp.580–583, 2011.
[6]. R. Hasanah, E. Daningsih, Titin. “The analysis of nutrient and fiber content of banana (Musa paradisiaca) sold in Pontianak, Indonesia”. Biofarmasi (Rumphius J.Nat. Prod. Biochem, Vol. 15, Issue 1, pp. 21- 25, 2017.
[7]. N. Gandhi, D. Sirisha, Smita Asthana. “Germination of seeds in soil samples of heavy traffic zones of Hyderabad telangana, India”. Environmental Science-An Indian Journal. Vol. 10, issue 6, pp. 204-214, 2015.
[8]. N. Gandhi, D. Sirisha, Smita Asthana. “Determination of physico-chemical properties of different industrial wastewater of Hyderabad, India”. Int. Res. J. Environment Sci., Vol. 6, issue 3, pp.1-10. 2016.
[9]. D. Priyamvada, D. Sirisha and N. Gandhi. “Characterization of Prawn pond in around bhimavaram, West Godavari district, A.P”. International Journal of Research in Chemistry and Environment, Vol. 2, issue 1, pp. 251-254, 2012.
[10]. D. Priyamvada, D. Sirisha and N. Gandhi. “Study on the quality of water and soil from fish pond in around Bhimavaram west Godavari district, A.P. India”. International Research Journal of Environmental Sciences, Vol. 2, issue 1, pp. 58-62, 2013.
[11]. N. Gandhi, D. Sirisha and K.B. Chandra Sekhar. “Phytoremediation of Chromium and Fluoride in Industrial wastewater by using aquatic plant Ipomea aquatic”. South pacific journal of Pharma and Bio Sciences, Vol. 1, issue 1, pp. 001-004, 2013.
[12]. N. Gandhi, J. Sridhar, A. Pllavi et al., “Germination Growth, Physiological and Biochemical response of pigeon pea (Cajanus cajan) under varying concentrations of copper (Cu), lead (Pb), manganese (Mn) and barium (Ba)”. International journal of research and review. Vol. 7, issue 3, pp. 321-347, 2020.
[13]. N. Gandhi, A. Sree lekha, S. Priyanka et al., “Impact of climatic and edaphic factors on germination, growth, physiological and biochemical response of pigeon pea (Cajanus cajan)”. Noble international journal of agriculture and food technology. Vol. 2, issue 8, pp. 54-84, 2020.
[14]. N. Gandhi, K. Rahul, N. Chandana, B. Madhuri, D. Mahesh. “Impact of ultraviolet radiation on seed germination, growth and physiological response of Bengal gram (Cicer arietinum L.) and Horse gram (Macrotyloma uniflorum L.)”. Journal of Biochemistry Research. Vol. 2, issue 1, pp. 019–0034, 2019.
[15]. M. Z. Iqbal, K. Rahmati., "Tolerance of Albizia lebbeck to Cu and Fe application," Ekologia (CSFR), Vol. 11, pp. 427-430, 1992.
[16]. C.H. Chou, C.H. Muller, "Allelopathic Mechanism of Arctostaphylos glandulosa, var. zacaensis," Am. Midl. Nat., Vol. 88, pp. 324-347, 1972.
[17]. N. Gandhi, D. Sirisha, Smita Asthana. “Phytoremediation of Fluoride (F-) from water using germinated seeds”. International journal of advanced Research in Engineering and Applied Sciences. Vol. 5, issue 7, pp.16 – 28, 2016.
[18]. A.A. Baki, J. D. Anderson, "Vigour Determination in Soybean Seed by Multiple Criteria”," Crop Science, Vol. 13, pp. 630-633, 1993.
[19]. J.D. Bewly, B. M. Black, "Physiology and Biochemistry of Seeds in Relation to Germination. Springer Ver- lag, New York," pp. 40-80, 1982.
[20]. A. Gang, A. Vyas, H. Vyas, "Toxic effect of heavy metals on germination and seedling growth of wheat," Journal of Environmental Research and Development. Vol. 8, pp. 206-213, 2013.
[21]. N. Gandhi, I. Prudhvi Raj, M. Maheshwar and D. Sirisha. “Germination, Seedling growth and biochemical response of Amaranthus (Amaranthus tricolour L.) and Sesame (Sesamum indicum L.) at varying Chromium Concentrations”. International Journal of Plant & Soil Science. Vol. 20, issue 5, pp. 1-16, 2017.
[22]. K.S. Ganesh, L. Baskaran, A.A. “Chidambaram, and P. Sundara, "Influence of chromium stress on pro- line accumulation in soybean (Glycine max L. Merr.) Genotypes," Global Journal of Environmental Research. Vol. 3, pp. 106-108, 2009.
[23]. Y. Ozdener, B.K. Aydin, S.F. Aygun, F. Yurekli, "Effect of hexavalent chromim on the growth and physiological and biochemical parameters on Brassica oleracea L. var. acephala DC”," Acta Biologica Hungarica. Vol. 62, pp. 463-476, 2011.
[24]. A. Hira, A.B. Ahmed, A. Farah, A.S. Muhammad, "Phytotoxicity of chromium on germination, growth and biochemical attributes of Hibiscus esculentus L," American Journal of Plant Sciences. Vol.4, pp. 2431-2439, 2013.
[25]. D.I. Arnon, "Copper enzymes in isolated chloroplasts, polyphenol oxidase in Beta vulgaris," Plant Physiology, Vol. 24, pp. 1-15, 1949.
[26]. J.R. Peralta, J.L. Gardea, K. J. Torresdey, E. Tiemann, S. Gomez, S. Arteaga, et al., "Uptake and effects of five heavy metals on seed germination and plant growth in Alfalfa (Medicago sativa L.)”," Bulletin of Environmental Contamination and Toxicology. Vol. 66, pp. 727-734, 2001.
[27]. R. Haribabu, P. Yugandhar, N. Savithramma. “Synthesis, characterization and antimicrobial studies of bio silica nanoparticles prepared from Cynodon dactylon L., a green approach. Bull. Mater. Sci. Vol. 41:65, pp. 1- 8, 2018.
[28]. P. Saritha, N. Gandhi and D. Sirisha Fourier Transform Infrared Spectroscopic Analysis of Medicinal Plant (Bhringaraj) from the Duvva Village West Godavari District, Andhra Pradesh, India”. CVR journal of Science and Technology. Vol.7, pp.101-104, 2014.
[29]. A. Alemdar, M. Sain. “Isolation and characterization of nanofibers from agricultural residues: wheat straw and soy hulls”. Bioresource Technology, Vol. 99, pp. 1664-1671, 2008.
[30]. R. Gnanasambandam, A. Protor. “Determination of pectin degree of esterification by diffuse reflectance fourier transform infrared spectroscopy”. Food Chemistry journal, Vol. 68, pp.327-332, 2000.
[31]. N. Gandhi, D. Sirisha and Smita Asthana. “Microwave Mediated Green Synthesis of Lead (Pb) Nanopacticles and its Potential Applications”. International Journals of Engineering Sciences and Research Technology. Vol. 7, issue 1, pp. 623 – 644, 2018.
[32]. N. Gandhi, D. Sirisha and Smita Astana. “Microwave Mediated Green Synthesis of Copper Nanoparticles using Aqueous Extract of Piper Nigrum Seeds and Particles Characterization”. Iaetsd Journal for Advance Research in Applied Science, Vol. 5, issue 2, pp. 859-870, 2018.
[33]. S.S. Nath, D. Chakdar, G. Gope, D.K. Avasthi. “Effect of 100 MeV nickel ions on silica coated ZnS quantum dots”. Journal of Nanoelectronics and optoelectronics. Vol. 3, Issue.2, pp.180- 183, 2008.
[34]. S. Nath, D. Chakdar. “Synthesis of CdS and ZnS Quantum Dots and Their Applications in Electronics”, Nanotrends. 2007.
[35]. R. Das, S.S. Nath, D. Chakdar, G. Gope, R. Bhattacharjee. “Synthesis of silver nanoparticles and their optical properties”. Journal of Experimental Nanoscience. Vol. 5, Issue.4, pp. 357-362, 2009.
[36]. B.D. Hall, D. Zanchet, D. Ugarte, D. “Estimating nanoparticle size from diffraction measurements”. Journal of applied crystallography. Vol. 33, Issue.6, pp.1335-1341, 2000.
[37]. N. Gandhi, Y. Shruthi, G. Sirisha and C.R. Anusha. “Facile and Eco-Friendly Method for Synthesis of Calcium Oxide (CaO) Nanoparticles and its Potential Application in Agriculture”. The Saudi Journal of Life Sciences. Vol. 6, issue 5, pp. 89-103, 2021.
[38]. Y. Sun, J. Xu, X. Miao, X. Lin, W. Liu, H. Ren. “Effects of exogenous silicon on maize seed germination and seedling growth”. Scientific Reports. Vol. 11, pp. 1014 – 1028, 2021.
[39]. Y. Zhu, H. Gong. “Beneficial effects of silicon on salt and drought tolerance in plants”. Agron. Sustain. Dev. Vol. 34, issue 2, pp. 455–472, 2013.
[40]. J. Meng, L. Cui, J.W. Han, M. Zhang. Advances in studies on the level of soil silicon and the effect of vegetable application. Anhui Agric. Sci. Bull. Vol. 19, issue 17, pp. 63–66, 2013.
[41]. S.V. Raskar, S.L. Laware. Effect of zinc oxide nanoparticles on cytology and seed germination in onion. International journal of current microbiology and applied sciences. Vol.3, Issue.2, pp. 467- 473, 2014.
[42]. N. Karimi, S. Minaei, M. Almassi, and A. R. Shahverdi. “Application of silver nano-particles for protection of seeds in different soils”. Afr. J. Agric. Res. Vol.7, issue 12, pp. 1863-1869, 2012.
[43]. M. H. Siddiqui and M. H. Al-Whaibi. “Role of nano-SiO2 in germination of tomato (Lycopersicum esculentum seeds Mill.)”. Saudi. J. Biol. Sci. Vol. 21, issue 1, pp. 13-17, 2014.
[44]. P. Zuccarini. “Effects of silicon on photosynthesis, water relations and nutrient uptake of Phaseolus vulgaris under NaCl stress”. Biologia Plantarum, Vol. 52, pp.157-160, 2008.
[45]. S.K. Lee, E.Y. Sohn, M. Hamayun, L.Y. Yoon, I.J. Lee. “Effects of silicon on growth and salinity stress of soybean plant grown under hydroponic system”. Agroforest Syst, Vol. 80, pp. 333-430, 2010.
[46]. C.W. Lee, S. Mahendra, K. Zodrow, D. Li, Y. Tsai, J. Braam, P. J. J. Alvarez. “Developmental phytotoxicity of metal oxide nanoparticles to Arabodopsis thaliana”. Environ. Toxicol. Chem. Vol. 29, pp. 669-675, 2010.
[47]. X.D. Wang, C. Ou-yang, Z. Fan, S. Gao. F. Chen, L. Tang. “Effects of exogenous silicon on seed germination and antioxidant enzyme activities of Momordica charantia under salt stress”. Journal of Animal & Plant Science, Vol. 6, pp.700-708, 2010.
[48]. X. Wang, Z. Wei, D. Liu, G. Zhao. “Effects of NaCl and silicon on activities of antioxidative enzymes in roots, shoots and leaves of alfalfa”. African Journal of Biotechnology, Vol. 10, pp.545-549, 2011.
[49]. L. Yin, Y. Cheng, B. Espinasse, P. B. Colman, M. Auffan, M. Wiesner, J. Rose, J. Liu, and E. S. Bernhardt. “More than the Ions: The effects of silver nanoparticles on Lolium multiflorum”. Environ. Sci. Technol. Vol. 45, pp. 2360–2367, 2011.
[50]. A. Parveen, S. Rao. Effect of nanosilver on seed germination and seedling growth in Pennisetum glaucum. J. Clust. Sci. Vol. 26, pp. 693-701, 2014.
[51]. Y. Jyothsna, U. Pathipati. “Environmental effects of nanosilver: impact on castor seed germination, seedling growth, and plant physiology”. Environ. Sci. Pollut. Res. Vol. 20, pp. 8636–8648, 2013.
[52]. M. Haghighi, Z. Afifipour, M. Mozafarian. “The effect of N-Si on Tomato seed germination under salinity levels. J.Biol.Environ.Sci. Vol.6, issue 16, pp.87-90, 2012.
[53]. A.H. Alsaeedi, M.M. Elgarawany, H.EI-Ramady, T. Alshaal, A.O.A. AL- otaibi. “Application of silica nanoparticles induces seed germination and growth of cucumber (Cucumis sativus)”. JKAU; met.Env. & Arid Land Agric. Sci. Vol. 28, issue 1, pp.57-68, 2019.
[54]. Tapan, S. Kundu, A. Subba Rao. “Impact of SiO2 and Mo Nano Particles on Seed Germination of Rice (Oryza Sativa L.)”. International Journal of Agriculture and Food Science Technology. Vol. 4, Issue. 8, pp. 809-816, 2013.
[55]. A. Vashisth, S. Nagarajan. “Effect on germination and early growth characteristics in sunflower (Helianthus annuus) seeds exposed to static magnetic field”. J Plant Physiol. Vol. 167, pp.149-156, 2010.
[56]. L. Bao-shan, D. Shao-qi, L. Chun-hui, F. Li-jun, Q. Shu-chun, Y. Min. “Effects of TMS (nanostructured silicon dioxide) on growth of Changbai larch seedlings”. Journal of Forestry research, Vol. 15, pp.138-140, 2004.
[57]. H. Zhu, J.Q. Han, Y. Jin. “Uptake, translocation, accumulation of manufactured iron oxide nano particles by pumpkin plants”. Journal of Environmental Monitoring. Vol. 10, pp.713-717, 2008.
[58]. P. Yugandhar, N. Savithramma. “Green synthesis of calcium carbonate nanoparticles and their effects on seed germination and seedling growth of Vigna mungo (L). Hepper. International journal of advanced research. Vol. 1, issue 8, pp.89-103, 2013.Citation
N. Gandhi, Sree laxmi, D. Madhusudhan Reddy, Ch. Vijaya, "Microwave Mediated Green Synthesis of Silica Nanoparticles, Characterization, Antimicrobial Activity, Promising Applications in Agriculture," World Academics Journal of Engineering Sciences, Vol.9, Issue.4, pp.1-15, 2022 -
Open Access Article
Performance Analysis of TCSC with Firing Angle Determination Based on Random Forest Algorithm
Niharika Agrawal, Faheem Ahmed Khan, Mamatha Gowda
Research Paper | Journal-Paper (WAJES)
Vol.9 , Issue.4 , pp.16-25, Dec-2022
Abstract
In order to meet the rising power demand, the options are to increase the generation and transmission facilities or to install more power plants. But installation of new power stations is costly matter and needs huge investment. So, it is desired to increase the power transfer capacity of the existing system. In the proposed work the use of fixed capacitors and Power -Electronics-based series FACTS device TCSC are done to increase the power transfer capacity of the system. The key contribution of this paper is the firing angle prediction by Random Forest Machine Learning Algorithm (RFMLA) for the various modes of TCSC. The trained data of input power and angle is loaded into the system and then firing angle prediction is done over the new data. Many decision trees are created for the input power and firing angle using MATLAB coding. The final value of firing angle is selected by the algorithm. The power flow and THD results are shown. FFT analysis tool in Powergui block is used to calculate THD voltage without compensation and then after using TCSC, combination of both FC and TCSC. The main issues and challenges in today’s smart power systems are meeting power demand and power quality problems like voltage sag and voltage swell created due to disturbances or faults, stability, contingency and congestion management with taking care of environment. The TCSC is capable of meeting all these challenges. The novelty here is the appropriate prediction of firing angle based on RFMLA.Key-Words / Index Term
Capacitor, Inductive ,Power quality, Total Harmonic Distortion, VoltageReferences
[1]. N.G. Hingorani, L. Gyugyi, “Understanding FACTS: Concepts and Technology of Flexible AC Transmission Systems,” IEEE Press, New York, 1999.
[2]. Sahil Mehta, Surya Prakash, “Performance Evaluation of FACTS Controllers for Short Transmission Line,” International Journal of Applied Engineering Research, Vol.13,Issue.7 pp. 5140-5153,2018.
[3]. Surender Reddy Salkuti, ”Improvement of Transient Stability using TCSC,” International Journal on Electrical Engineering and Informatics,Vol.10,Issue. 3, pp 526-541,2018.
[4]. M.Karthikeyan, Degu Menna Eligo, “Enhancement of Power Transfer Capability in a Long Transmission line using series FACTS Device,” International Journal of Engineering ,Science and Mathematics, Vol.8,Issue.1,pp. 34-40,2019.
[5]. Aanand Kumbhar, Pravin G. Dhawale, Shobha Kumbhar, Uday Patil, Pravin Magdum ,”A comprehensive review: Machine learning and its application in Integrated Power System,” Energy Reports, Vol.7, pp.5467–5474,2021.
[6]. R.Gandotra,K. Pal,” FACTS Technology: A Comprehensive Review on FACTS Optimal Placement and Application in Power System, “Iranian Journal of Electrical and Electronic Engineering ,Vol. 18, Issue.3,pp.1-14,2022.
[7]. G.Das, R. Panda, L. Samantaray, S. Agrawal,” A Novel Non-Entropic Objective Function for Multilevel Optimal Threshold Selection Using Adaptive Equilibrium Optimizer,” Iranian Journal of Electrical and Electronic Engineering, Vol. 18, Issue.2,pp.1-10,2022.
[8]. Chaisit Wannoi, Narumon Wannoi ,”Techniques for Assessment Inter-Area Power Transfer Capacity for Large Power Systems to Improve System Stability ,“SNRU Journal of Science and Technology, Vol.13, Issue.3,pp.126?134,2021.
[9]. Wei Li,” Optimization and Application of Random Forest Algorithm for Applied Mathematics Specialty,” Hindawi Security and Communication Networks, Vol.2022, pp.1-9.
[10]. Suzhen Wang, Zhanfeng Zhang, Shanshan Geng ,Chaoyi Pang,” Research on Optimization of Random Forest Algorithm Based on Spark,” Computers, Materials & Continua, Tech-Science Press,pp.1-11,2022
[11]. Niva Mohapatra, K. Shreya and Ayes Chinmay,” Optimization of the Random Forest Algorithm,” Lecture Notes on Data Engineering and Communications Technologies 37, Springer Nature Singapore Pvt Ltd, pp 201-210,2020.
[12]. Marco Oyarzo Huichaqueo,” Machine Learning Method for Knee Osteoarthritis Detection from Magnetic Resonance Imaging: A 3-D Independent Component Analysis-Based Approach,” World Academics Journal of Engineering Sciecnes,Vol.8,Issue.04,pp.01-04,2021.
[13]. Armin Hassanzadeh Hassanabad, Yaser Sarsabahi, Aashish Kumar Bohre, Mlungisi Khulani Ngwenyama,” Design and Simulation of Space Vector Pulse Width Modulation Inverter based Transformer-less in small Wind Turbines,” World Academics Journal of Engineering Sciences,Vol.9, Issue.2,pp.01-08,2022.
[14]. Johan Note and Maaruf Ali,” Comparative Analysis of Intrusion Detection System Using Machine Learning and Deep Learning Algorithms,” Annals of Emerging Technologies in Computing, Vol. 6, Issue. 3, ,pp.19-36,2022.
[15]. Musa Mojarad, Afsaneh Haghanin Nia, Neda Galehdari, Khayronsa Bazarganzadeh ,”Identifying Internet Crime Using Mamdani Fuzzy Rules and Fuzzy Classification Algorithm,” World Academics Journal of Engineering Sciences,Vol.8, Issue.2, pp.18-23, 2021.Citation
Niharika Agrawal, Faheem Ahmed Khan, Mamatha Gowda, "Performance Analysis of TCSC with Firing Angle Determination Based on Random Forest Algorithm," World Academics Journal of Engineering Sciences, Vol.9, Issue.4, pp.16-25, 2022 -
Open Access Article
S.O. Okpo, I. Edeh
Research Paper | Journal-Paper (WAJES)
Vol.9 , Issue.4 , pp.26-33, Dec-2022
Abstract
Rubber seed husk is currently being discarded as agricultural waste, leading to economic loss. The current work assesses the possibility of converting this waste into activated carbon for potential use as an adsorbent. This was achieved using the physical method at 450oC for 1h and the chemical activation method through a one-step activation process with H3PO4 as the activating agent and an impregnation ratio of 1:1. The physicochemical properties of the formulated activated carbon were investigated, and functional groups were assessed using Fourier transform infrared spectroscopy (FTIR). The results of the physicochemical properties of the formulated activated carbon prepared using the physical method were: bulk density (0.4784 g/mL), pH (6.4), moisture content (0.730%), ash content (29.302%), volatile matter (21.66%), iodine number (16.624 mg/g), and surface area (525.4 m2/g). Results of the physicochemical properties of activated carbon prepared using chemical methods were: bulk density (0.4764 g/mL), pH (6.2), moisture content (0.2976%), ash content (29.302%), volatile matter (28.788%), iodine number (18.009 mg/g), and surface area (563.8m2/g). Regardless of method employed, FTIR investigations have revealed presence of alcohols, phenols, aldehydes, aromatics, amines, amides, carboxylic acids, esters, alkenes, and alkanes in manufactured activated carbon. The obtained result shows that high-quality activated carbon can be formulated from rubber seed husks using either physical or chemical methods.Key-Words / Index Term
Activated carbon; Adsorbent; Chemical activation; Physical activation; Pollution, Rubber seed husk; Wastewater.References
[1]. P. Susheela, R. Radha, “Production of activated carbon from dry coconut shell and its efficacy in treating waste water”, IJCBS research paper, Vol.1, Issue. 10, pp.1-9, 2015.
[2]. S. Singh, I.J. Chaudhary, P. Kumar, “Utilization of Low-cost Agricultural Waste for Removal of Toxic Metals from Environment: A Review.” Int. J. Sci. Res. In Biological Sciences Vol.6, Issue.4, pp.56-61, 2019. DOI:https://doi.org/10.26438/ijsrbs/v6i4.5661
[3]. M. Gericke, J. Trygg, P. Fardim, “Functional cellulose beads: Preparation, characterization and applications,” Chemical Reviews, Vol 113, issue, 7, pp 4812–4836, 2013.
[4]. S.N. Ndung’u, E.W.Nthiga, R.N. Wanjau, J. Ndiritu, “Adsorption Studies of Lead (II) Ions from a Synthetic Media using Jackfruit (Artocarpus heterophyllus L.) Rags: Kinetics, Equilibrium and Thermodynamic Studies”, International Journal of Scientific Research in Research Paper.Chemical Sciences, Vol.8, Issue.4, pp.05-12, 2021.
[5]. M.J. Hao, M.Q. Qiu, H .Yang, B.W. Hu, X.X. Wang, “Recent advances on preparation and environmental applications of MOF-derived carbons in catalysis”, Sci. Total. Environ. Vol. 760, pp.1-114, 2021.
[6]. R. Galvao, A.A. da Silva Moretti, F. Fernandes, E.K. Kuroda, “Post-treatment of stabilized landfill leachate by upflow gravel filtration and granular activated carbon adsorption” Environ. Technol. Vol.42, Issue.26, pp.4179-4188, 2020.
[7]. W. Tongpoothorn, M. Sriuttha, P. Homchan, S. Chanthai, C. Ruangviriyachai, “Preparation of activated carbon derived from Jatropha curcas fruit shell by simple thermo chemical activation and characterization of their physicochemical properties”, Chem. Eng. Res. Des., Vol. 89, pp. 335-340, 2011.
[8]. L. Tan, Z. Ma, K.Yang, Q. Cui, K. Wang, T. Wang, G. Wu, J. Zheng, “Effect of three artificial aging techniques on physicochemical properties and Pb adsorption capacities of different biochars”, Science of The Total Environment, Vol.699,134223, 2020. doi:10.1016/j.scitotenv.2019.134223
[9]. V. Fierro, G. Muniz, A.H. Basta, H. El-Saied, A. Celzard, “Rice straw as precursor of activated carbons: activation with ortho-phosphoric acid”, Journal of Hazardous Materials, Vol.181, pp. 27-34, 2010.
[10]. M. Goncalves, C.S. Castro, I.K.V. Boas, F.C. Soler, E.D.C.Pinto, R.L. Lavall, W.A. Carvalho, “Glycerin waste as sustainable precursor for activated carbon production: adsorption properties and application in supercapacitors.”, Journal of Environmental Chemical Engineering, Vol.7, Issue. 3, 103059, pp. 1-11, 2019. doi:10.1016/j.jece.2019.103059
[11]. M. Plaza-Recobert, G. Trautwein, M. Pérez-Cadenas, J. Alcañiz-Monge, “Preparation of binderless activated carbon monoliths from cocoa bean husk”, Microporous Mesoporous Mater, Vol.243, pp. 28–38, 2017.
[12]. L.O. Ekebafe, J.E. Imanah, F.E. Okieimen, “Effect of carbonization on the processing characteristics of rubber seed shell”, Arabian Journal of Chemistry, Vol.10, pp.174–178, 2017.
[13]. Y. Sudaryanto, S.B. Hartono, W. Irawaty, H. Hindarso, S. Ismadji, “High surface area activated carbon prepared from cassava peel by chemical activation”, Bioresour. Technol. Vol. 97, No. 5, pp. 734–39, 2006.
[14]. D. Mohan, C.U. Pittman, “Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water”, J. Hazard. Mater, Vol. 137, Issue. 2, pp. 762–811, 2006. doi:10.1016/j.jhazmat.2006.06.060
[15]. A. D?browski, P. Podko?cielny, Z. Hubicki, M. Barczak, “Adsorption of phenolic compounds by activated carbon : A critical review”, Chemosphere, Vol. 58, Issue. 8, pp.1049–70, 2005. doi:10.1016/j.chemosphere.2004.09.067
[16]. O. ?ahin, C. Saka, “Preparation and characterization of activated carbon from acorn shell by physical activation with H2O–CO2 in two-step pretreatment”, Bioresour. Technol. Vol. 136, Issue. 3, pp. 163–68, 2013. doi:10.1016/j.biortech.2013.02.074
[17]. M.J. Ahmed, S.K. Theydan, “Physical and chemical characteristics of activated carbon prepared by pyrolysis of chemically treated date stones and its ability to adsorb organics” Powder Technology, Vol .229, pp. 237–245, 2012. http:.doi.org/10.1016/j.powtec.2012.06.043
[18]. P. Pragya, S. Sripal, Y. Maheshkumar, “Preparation and study of properties of activated carbon produced from agricultural and industrial waste shells” Research Journal of Chemical Sciences, Vol. 3, pp.12-15, 2013.
[19]. P.C. Madu, L. Lajide, “Physicochemical characteristics of activated charcoal derived from melon seed husk”, Journal of Chemical and Pharmaceutical Research, Vol. 5, Issue. 5, pp. 94-98, 2013.
[20]. Indonesia National Standard (SNI) 60-3730-1995
[21]. E.T. Evwierhoma, O.D. Madubiko, A. Jaiyeola, “Preparation and characterization of activated carbon from bean husk”, Nigerian Journal of Technology (NIJOTECH), Vol. 37, No.3, pp. 674–678, 2018. http://dx.doi.org/10.4314/njt.v37i3.17
[22]. V.E. Efeovbokhan, E.E. Alagbe1, B. Odika, R. Babalola, T.E. Oladimeji, O.G. Abatan, E.O. Yusuf, “Preparation and characterization of activated carbon from plantain peel and coconut shell using biological activators”, Journal of Physics: Conference Series 1378 (2019) 032035, 2019. doi:10.1088/1742-6596/1378/3/032035
[23]. A.M. Abdul Raheem, E.A. Adeoye, “Preparation and characterization of steam activated chicken eggshell for gaseous pollutant adsorption’, Arid Zone Journal of Engineering, Technology and Environment, Vol. 18, Issue. 1, pp. 31-40, 2022.
[24]. American Society for Testing and Materials-ASTM, Standard for method for determination of iodine number of activated carbon ASTM D 4607-86, Philadelphia, PA: ASTM Committee on Standards, 1986.
[25]. S.M. Anisuzzaman, C.G. Joseph, Y.H. Taufiq-Yap, D. Krishnaiah, V.V. Tay, “Modification of commercial activated carbon for the removal of 2,4-dichlorophenol from simulated wastewater”, Journal of King Saud University-Science, Vol. 2, Issue. 4, pp. 318-330, 2015.
[26]. F.T. Ademiluyi, E.O. David-West, “Effect of chemical activation on the adsorption of heavy metals using activated carbons from waste materials”, ISRN Chemical Engineering, Vol. 2012, No.1, pp.1-5, 2012.
[27]. E.S. Sanni, M.E. Emetere, J.O. Odigure, V.E. Efeovbokhan, O. Agboola, E.R. Sadiku, “Determination of optimum conditions for the production of activated carbon derived from separate varieties of coconut shells”, Int. J. Chem. Eng. Vol. 2017, pp.1– 16, 2017.
[28]. P. Sugumaran, V.P. Susan, P, Ravichandran, S. Seshadri, “Production and characterization of activated carbon from banana empty fruit bunch and delonix regia fruit pod”, Journal of Sustainable Energy & Environment ,Vol. 3, pp. 125-132, 2012.
[29]. O.A. Ekpete, A.C. Marcus, V. Osi, “Preparation and characterization of activated carbon obtained from plantain (musa paradisiaca) fruit stem”, Journal of Chemistry , Vol. 2017, 6 pages, 2017. https://doi.org/10.1155/2017/8635615.
[30]. S. Siahaan, M. Hutapea, R. Hasibuan, “Penentuan kondisi optimum suhu dan waktu karbonisasi pada pembuatan arang dari sekam padi “, Jurnal Teknik Kimia, Vol. 2, Issue.1, pp.26-30, 2013.
[31]. J. M. Marton, M.G.A. Felipe, E. Almeida, J.B. Silva, A. Pessoa, “Evaluation of the activated charcoals and adsorption conditions used in the treatment of sugarcane bagasse hydrolysate for xylitol production”, Braz. J. Chem. Eng. Vol. 23, Issue. 1, pp. 9-21, 2006.
[32]. O.A. Ekpete, M.J.N.R. Horsfall, “Preparation and characterization of activated carbon derived from fluted pumpkin stem waste (Telfairia occidentalis Hook F)”, Research Journal of Chemical Sciences, 1(3), 10-17, 2011.
[33]. R. Malik, D. Ramteke, S. Water, “Physico-chemical and surface characterization of adsorbent prepared from groundnut shell by ZnCl2 activation and its ability to adsorb colour”, Indian Journal of Chemical Technology. Vol. 13, pp. 329-333, 2006.
[34]. A. Nyamful, E.K. Nyogbe, L. Mohammed, M.N. Zainudeen, S.A. Darkwa, I. Phiri, M. Mohammed, J.M. Ko, “Processing and characterization of activated carbon from coconut shell and palm kernel shell waste by H3PO4 activation”, Ghana Journal of Science, Vol. 61, Issue. 2, pp. 91104,2020. https://Dx.Doi.Org/10.4314/Gjs.V61i2.9
[35]. A. Ahmad, H.M Al-Swaidan, A.H. Alghamdi, “Production of activated carbon from raw date palm fronds by Zncl2 activation”, J. Chem. Soc. Pak., Vol. 37, Issue. 6, pp. 1081-1087, 2015.
[36]. M.M. Aji, B. Gutti, B.K. Highina, “Production and characterization of activated carbon (ac) from groundnut shell and its application in water treatment”, University of Maiduguri, Faculty of Engineering Seminar Series, Vol. 8, pp.91-98, 2017.
[37]. D. Anis, M.A.M Ishak, A.G. Zaidi, I. Khudzir, M.N. Iqbaldin, M.O. Uwaisulqarni, W.I Nawawi, “Production of rubber seed pericarp based activated carbon using microwave-induced different chemical activating agent”, International Journal of Scientific and Research Publications, Vol. 4, Issue 7, pp.1-8, 2014.
[38]. J.T. Nwabanne, P.K. Igbokwe, “Preparation of activated carbon from nipa palm nut: influence of preparation conditions”, Research Journal of Chemical Sciences, Vol. 1, Issue. 6, pp. 53-58, 2011.
[39]. A.B.D. Nandiyanto, R.Oktiani, R. Ragadhita, “ How to Read and Interpret FTIR Spectroscope of Organic Material”, Indonesian Journal of Science & Technology, Volume 4, Issue 1, pp. 97-118, 2019.
[40]. O. Hayet, G. Najes, “Removal of Cd (II) from Phosphoric Acid Solution by Adsorbents: Equilibrium and Kinetic Studies”, Chemical Science Transactions, vol. 2, 357, 2013.
[41]. J. Barkauskas, M. Dervinyte, “An investigation of the functional groups on the surface of activated carbons”, J.Serb.Chem.Soc. volume 69, issue 5, pp. 363–375, 2004.
[42]. K. Ahmida , M. Darmoon, F. Al-Tohami, M. Erhayem, M. Zidan, “Effect of physical and chemical preparation on characteristics of activated carbon from agriculture solid waste and their potential application”, International Conference on Chemical, Civil and Environmental Engineering (CCEE-2015), pp. 83-87, 2015. http://dx.doi.org/10.15242/IICBE.C0615015
[43]. V. Strelko Jr, D.J. Malik, M. Streat, “Characterisation of the surface of oxidised carbon adsorbents”, Carbon , Vol. 40, Issue. 1, pp. 95-104, 2002.
[44]. R. Xie, Y. Jin, Y. Chen, W. Jiang, “The importance of surface functional groups in the adsorption of copper onto walnut shell derived activated carbon”, Water Science and Technology, Vol. 76, pp. 3022-3034, 2017.
[45]. Y. Bian, Z.Y. Bian, J.X. Zhang, A.Z. Ding, S.L. Liu, H. Wang, “Effect of the oxygen-containing functional group of graphene oxide on the aqueous cadmium ions removal”, Applied Surface Science, Vol. 329, pp.269-275, 2015.
[46]. H.Y. Wang, B. Gao, S.S. Wang, J. Fang, Y.W. Xue, K. Yang, “Removal of Pb(II), Cu(II), and Cd(II) from aqueous solutions by biochar derived from KMnO4 treated hickory wood”, Bioresource Technology, Vol. 197, pp. 356-362, 2015. DOI: 10.1016/j.biortech.2015.08.132Citation
S.O. Okpo, I. Edeh, "Formulation and Characterization of Activated Carbon from Rubber Seed Husk Using Physical and Chemical Methods," World Academics Journal of Engineering Sciences, Vol.9, Issue.4, pp.26-33, 2022 -
Open Access Article
Ship-Generated Marine Pollution and the Warri Port Environment
I. Njoku, E. M. Oluwaremi
Research Paper | Journal-Paper (WAJES)
Vol.9 , Issue.4 , pp.34-43, Dec-2022
Abstract
The study examines ship-generated marine pollution at Warri port with the intent of finding the cause and effect of such unwholesome practice. The primary and experimental data were employed for the study. The primary data were obtained through structured questionnaires administered to different categories of respondents including the crew, shippers, ship and port operators. Whereas the experimental data were generated from the wastewater collected from the port berthing areas where ships slated for cargo handling operations had anchored for more than 24 hours for one week. The research employed the use of descriptive statistics to analyse primary data while a physiochemical and microbiological analysis of samples of ships’ wastewater was conducted in Laboratory to determine the status of marine pollution in the Warri port environment. The Laboratory analysis comprises microbiological, chemical, and physical parameters of wastewater samples. The following parameters were tested: pH, total dissolved solids, total hetero-trophic bacteria, total hetero-trophic fungi, zinc, lead, iron, copper, total oil and grease, conductivity, etc. The result reveals that the port and its environs are polluted. It, therefore, suggests a synergy between regulatory agents and private cleaning companies for effective monitoring and controlling of pollution in seaports. The study also recommends that the government encourages public ownership and private sector operations of the port infrastructure in Nigeria.Key-Words / Index Term
marine pollution, ship-generated wastewater, physico-chemical and microbiological analysisReferences
[1] V. E. Akpan and D. O. Olukanni, “Hazardous Waste Management”: An African Overview. Recycling. Vol.5, Issue.15, pp.1-24, 2020.
[2] Ocean Alive conservation Trust “What is Marine Pollution" OCEANS ALIVE TRUST, 2022, (oceans-alive.org).
[3] J. Verma, H. Pant, S. Sing and A. Tiwari, “Marine Pollution, Sources, Effect and Management”, Book Chapter, Publisher: Society of Biological Sciences and Rural Development, India, pp.270 -276, 2020.
[4] Allianz Global Corporate and Speciality, 2012.
[5] R. Justyna and N. Jacek, “Environmental Implications of Oil Spills from Shipping Accidents”, Journal of Environmental Contamination and Toxicology, 2010.
[6] S. O. Aghalino, "Oil Mineral Exploitation, Environmental Deterioration and Public Policy in Nigeria", Calabar Journal of Politics and Administration. Vol.2, Issue.122, pp.39-50, 2004.
[7] I. J. Alakpodia , “The Effect of Gas Flaring on the Microclimate and Adjacent Vegetation in Isoko Area. Unpublished M.Sc. Thesis, University of Lagos, Nigeria, 1980.
[8] Baird, J. “Oil Shame in Africa”, Newsweek 27, 2010.
[9] D. U. Ekwenna, “Analysis of Nigeria Potential Crude Oil Afreightment, The Politics of Crude Oil Afreightmnet in Nigeria”. Lagos Alpatrick Ltd, 2005.
[10] F. M. Al Fartoosi, "The impact of maritime oil pollution in the marine environment: case study of maritime oil pollution in the navigational channel of Shatt Al-Arab" (2013).World Maritime University Dissertations.
[11] F. Ufia, “Marine Environmental Protection and Safety”, Unpublished Lecture Material at the Certified Institute of Shipping of Nigeria, Onne, 2009.
[12] Ndukwe, “History and Statistical Survey of Oil Spillage in Nigeria”: The Environmental Hazard Journal of Social Science, Ibadan, pp. 34, 2000.
[13] NDHR Niger Delta Health Development Report. Port Harcourt, 2006.
[14] Niger Delta Environmental Survey, NDES, 2003.
[15] B. Simon, “Shipping Law. London, Cavendish Publishing Ltd. 2007.
[16] O. P. Egbejule “An Empirical Investigation on the Effect of Environmental Degradation and Poverty in Nigeria” International Journal of Innovative Science and Research Technology, Vol.6, Issue.10, 2021.
[17] O. Omoregie, “An Examination of the Sources of Nigerian Environmental Law” Ambrose Alli University Law Journal, Vol.11, Issue.1, 2016.
[18] A. A. Ikein, “The Impact of Oil on a Developing Economy: The Case of Nigeria”. New York and London: Praeger,1990.
[19] Oil spills: "Legacy of the Torrey Canyon". The Guardian. 24 June 2010, https://en.wikipedia.org/wiki/Torrey_Canyon_oil_spill.
[20] G. E. Etikerentse, “Nigerian Petroleum Law”, London: Macmillan.
[21] World Bank Policy and Research Bulletin, April – June, Vol.11, No. 2, 2000.
[22] D. E. Onwuegbuchunam, T. E. Ebe, L. I. Okoroji and A. E. Essien “An Analysis of Ship-Source Marine Pollution in Nigeria Seaports” Journal of Marine Science and Engineering,Vol.5, Issue.3, pp.39, 2017.
[23] I. Umo and S. Nitonye, “Effects and Solutions of Marine Pollution from Ships in Nigerian Waterways”. International Journal of Scientific & Engineering Research, Vol.6, Issue.9, pp.81-90, 2015.Citation
I. Njoku, E. M. Oluwaremi, "Ship-Generated Marine Pollution and the Warri Port Environment," World Academics Journal of Engineering Sciences, Vol.9, Issue.4, pp.34-43, 2022 -
Open Access Article
Y?ld?r?m Özüpak, Mehmet Ç?nar
Research Paper | Journal-Paper (WAJES)
Vol.9 , Issue.4 , pp.44-48, Dec-2022
Abstract
The increase in the use of portable electronic devices has increased the interest in studies on wireless charging applications technologies. The efficiency of this system is one of the most important parameters for the WPT system, which has become one of the popular research areas, especially in recent years, with technological developments. Many studies have been carried out using different techniques about the WPT system, which has advantages such as ease of use, no cable costs and freedom of movement. WPT systems, which are used in many application areas today, are considered to be the pioneers of the near future, especially for battery charging applications of electric vehicles. In this study, an application based on magnetic resonance coupling, which provides high efficiency wireless power transmission for electric vehicles, has been made. The analysis of the WPT transformer designed in the Finite Element Method (FEM) based ANSYS-Maxwell-3D environment has been made. The system parameters of the designed wireless power transmission system are obtained from an integrated platform ANSYS-Simplorer-Maxwell. It has been seen that the efficiency of the power obtained by integrated simulation studies is 88.6%.Key-Words / Index Term
WPT, Efficiency, Electric vehicles, FEM, ANSYS-Maxwell, TransformerReferences
[1]. L. Feng, L.Yanjie, Z.Siqi, Yifang C., Xuan S. and Yutong D. Wireless power transfer tuning model of electric vehicles with pavement materials as transmission media for energy conservation. Applied Energy 323 (2022) 119631
[2]. Y. Özüpak, Analysis of the Model Designed for Magnetic Resonance Based Wireless Power Transfer Using FEM. Journal of Engineering Research DOI: 10.36909/jer.17631, 2022
[3]. Y. Özüpak, Design and Efficiency Analysis of a Circular Coil Transformer for Wireless Power Transfer System of Electric Vehicles. Journal of Çukurova University Engineering Faculty, 37 (1), 209-219. DOI: 10.21605/cukurovaumfd.1095053, 2022
[4]. J. Deng, W. Li; Nguyen, T.D.; Siqi Li; Mi, C.C. "Compact and Efficient Bipolar Coupler for Wireless Power Chargers: Design and Analysis", Power Electronics, IEEE Transactions on, On page(s): 6130 - 6140 Volume: 30, Issue: 11, Nov. 2015.
[5]. Y. Özüpak, Design and Analysis of Different Transformer Models for Wireless Power Transfer Systems of Electric Vehicles", DUJE (Dicle University Journal of Engineering) 13:1 (2022), pp.11-18, Mar. 2022, doi:10.24012/dumf.1079729, 2022
[6]. M.Budhia, J.T Boys, G.A Covic, C. Y. Huang, "Development of a Single-Sided Flux Magnetic Coupler for Electric Vehicle IPT Charging Systems," Industrial Electronics, IEEE Transactions on , vol. 60, no.1, pp.318,328, Jan. 2013.
[7]. G. R. Nagendra, G. A. Covic and J. T. Boys, "Determining the Physical Size of Inductive Couplers for IPT EV Systems," in IEEE Journal of Emerging and Selected Topics in Power Electronics, vol. 2, no. 3, pp. 571-583, Sept. 2014.
[8]. Y. Yamada and T. Imura, "An Efficiency Optimization Method of Static Wireless Power Transfer Coreless Coils for Electric Vehicles in the 85 kHz Band Using Numerical Analysis," IEEJ, Transactions on Electrical and Electronic Engineering, Vol.17No.10, 2022.
[9]. Y. Yamada, K. Sasaki, T. Imura and Y. Hori, "Design Method of Coils for Dynamic Wireless Power Transfer Considering Average Transmission Power and Installation Rate," IEEE 6th Southern Power Electronics Conference (SPEC 2021), Kigali Rwanda , 2021
[10]. E. Ayd?n, A. Pashaei, E. Yildiriz, M. T. Aydemir, “ Design of a 2.2 kW Wireless Power Transfer System for Electric Vehicles”, Firat Unv. Journal of Science 30(3),1-6, 2018
[11]. R.Navid, W. Jun and Y. Xibo, In-Situ Measurement and Investigation of Winding Loss in High-Frequency Cored Transformers Under Large-Signal Condition. IEEE open journal Industry Applications, Vol. 3. 2022.
[12]. J.Sallan, J. L., Villa A., Llombart ve J. F., Sanz “Optimal design of ICPT systems applied to electric vehicle battery charge,” in IEEE Trans. on Industrial Electronics, vol. 56, no. 6, pp. 2140-2149, June 2009.
[13]. K. Aditya, Design And Implementation Of An Inductive Power Transfer System For Wireless Charging Of Future Electric Transportation” University of Ontario Institute of Technology Oshawa, Ontario, Canada, 2016
[14]. L. Siqi Mi, C.C.Wireless Power Transfer for Electric Vehicle Applications. IEEE J. Emerg. Sel. Top. Power Electron. 2015, 3, 4–17. 2015.
[15]. H. Wang and K. W. Eric Cheng, "A Special Magnetic Coupling Structure Design for Wireless Power Transfer Systems," 2022 IEEE 20th Biennial Conference on Electromagnetic Field Computation (CEFC), 2022, pp. 1-2, doi: 10.1109/CEFC55061.2022.9940745. 2022
[16]. S. S. Mohan, M. del Mar Hershenson, S. P. Boyd and T. H. Lee, "Simple accurate expressions for planar spiral inductances," in IEEE Journal of Solid-State Circuits, vol. 34, no. 10, pp. 1419-1424, Oct 1999.Citation
Y?ld?r?m Özüpak, Mehmet Ç?nar, "Analysis of Magnetic Resonance Coupled Wireless Power Transfer System Designed For Electric Vehicles With Finite Element Method Based ANSYS-Maxwell," World Academics Journal of Engineering Sciences, Vol.9, Issue.4, pp.44-48, 2022
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